Skeletal transformations of perfluoro-1-phenylindan under the action of antimony pentafluoride

被引：22

作者：

Karpov, VM ^{[1
]}

Mezhenkova, TV ^{[1
]}

Platonov, VE ^{[1
]}

Sinyakov, VR ^{[1
]}

机构：

[1] NN Vorozhtsov Inst Organ Chem, Novosibirsk 630090, Russia

来源：

JOURNAL OF FLUORINE CHEMISTRY | 2001年 / 107卷 / 01期

基金：

俄罗斯基础研究基金会;

关键词：

skeletal transformations; perfluorophenylindan; antimony pentafluoride; NMR spectroscopy; mass spectrometry;

D O I：

10.1016/S0022-1139(00)00346-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Perfluoro-1 -phenylindan (1) was obtained from perfluoroindan and pentafluorobenzene in the presence of SbF5. Compound 1 heated with antimony pentafluoride at 170 degreesC and then treated with water gave a mixture of perfluorinated 9-methylfluorene (5), 9-hydroxy-9-methylfluorsne (6), 9-methyl- 1,2.3.4.5,6,7,8-octahydroanthracene (7), 1,9-dimethyl-5,6,7,8-tetrahydro-beta -naphthindan (8). When heated with SbF5 in the presence of HF and then treated with water, compound 1 is transformed to a mixture of products 5. 6, perfluoro-1.2.3.3,5,6.7,8-octahydroanthracene (9), perfluoro-10-methyl-9(10H)anthracenone (10) and 10-H-perfluoro-10-methyl-9(10H)anthracenone (11). (C) 2001 Elsevier Science B.V. All rights: reserved.

引用

页码：53 / 57

页数：5

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