Cascade conversion of glucose to 5-hydroxymethylfurfural over Bronsted-Lewis bi-acidic SnAl-beta zeolites

被引：15

作者：

An, Hyejin ^{[1
]}

Kweon, Sungjoon ^{[1
]}

Kang, Dong-Chang ^{[2
]}

Shin, Chae-Ho ^{[2
]}

Kim, Jeong F. ^{[1
]}

Park, Min Bum ^{[1
]}

Min, Hyung-Ki ^{[3
]}

机构：

[1] Incheon Natl Univ, Dept Energy & Chem Engn, Incheon 22012, South Korea

[2] Chungbuk Natl Univ, Dept Chem Engn, Cheongju 28644, Chungbuk, South Korea

[3] LOTTE Chem Res Inst, Daejeon 34110, South Korea

来源：

KOREAN JOURNAL OF CHEMICAL ENGINEERING | 2021年 / 38卷 / 06期

关键词：

Beta Zeolite; Glucose Conversion; Cascade Reaction; 5-Hydroxymethylfurfural; Bi-acidic Catalysts; EFFICIENT CATALYST; LEVULINIC ACID; ISOMERIZATION; BIOMASS; QUANTIFICATION; TRANSFORMATION; DEALUMINATION; SUGARS; SITES;

D O I：

10.1007/s11814-021-0752-1

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The control of acidic properties in a catalyst is one of the key features of technology utilizing biomass for chemical production. In this study, the Bronsted and Lewis bi-acidic SnAl-beta zeolites with controllable acidity were successfully prepared by acid dealumination and isomorphic substitution of Al by Sn, and applied for the cascade conversion of glucose to 5-hydroxymethylfurfural (5-HMF). The Lewis acidity of the catalysts was increased as the higher concentration of nitric acid used for the dealumination process. The optimum portion of Lewis/(Bronsted+Lewis) ratio was investigated to maximize the yield of 5-HMF, which is converted from the glucose via fructose by the cascade reaction. The conversion of glucose was increased until the L/(B+L) ratio reached 0.89 and the selectivity to 5-HMF reached its maximum at the Lewis acid portion of 0.76 among the total acid sites.

引用

页码：1161 / 1169

页数：9

共 39 条

[1] New Frontiers in the Catalytic Synthesis of Levulinic Acid: From Sugars to Raw and Waste Biomass as Starting Feedstock
Antonetti, Claudia
Licursi, Domenico
Fulignati, Sara
Valentini, Giorgio
Galletti, Anna Maria Raspolli
[J]. CATALYSTS, 2016, 6 (12)
[2] Framework and Extraframework Tin Sites in Zeolite Beta React Glucose Differently
Bermejo-Deval, Ricardo
Gounder, Rajamani
Davis, Mark E.
[J]. ACS CATALYSIS, 2012, 2 (12): : 2705 - 2713
[3] Technology development for the production of biobased products from biorefinery carbohydrates-the US Department of Energy's "Top 10" revisited
Bozell, Joseph J.
Petersen, Gene R.
[J]. GREEN CHEMISTRY, 2010, 12 (04) : 539 - 554
[4] Efficient glucose dehydration to HMF onto Nb-BEA catalysts
Candu, Natalia
El Fergani, Magdi
Verziu, Marian
Cojocaru, Bogdan
Jurca, Bogdan
Apostol, Nicoleta
Teodorescu, Cristian
Parvulescu, Vasile I.
Coman, Simona M.
[J]. CATALYSIS TODAY, 2019, 325 : 109 - 116
[5] Chatterjee C, 2015, GREEN CHEM, V17, P40, DOI [10.1039/C4GC01062K, 10.1039/c4gc01062k]
[6] Catalytic Conversion of Glucose into 5-Hydroxymethyl Furfural Over Cu-Cr/ZSM-5 Zeolite
Chung, Nguyen Hoang
Oanh, Vo Thi
Thoa, Luong Kim
Hoang, Phan Huy
[J]. CATALYSIS LETTERS, 2020, 150 (01) : 170 - 177
[7] Catalytic Isomerization of Biomass-Derived Aldoses: A Review
Delidovich, Irina
Palkovits, Regina
[J]. CHEMSUSCHEM, 2016, 9 (06) : 547 - 561
[8] Selective catalytic reduction of NO with NH3 over Mo-Fe/beta catalysts: the effect of Mo loading amounts
Deng, Jianlin
Liu, Jixing
Song, Weiyu
Zhao, Zhen
Zhao, Liang
Zheng, Huiling
Lee, Alex Chinghuan
Chen, Yongsheng
Liu, Jian
[J]. RSC ADVANCES, 2017, 7 (12): : 7130 - 7139
[9] Selective Chemical Conversion of Sugars in Aqueous Solutions without Alkali to Lactic Acid Over a Zn-Sn-Beta Lewis Acid-Base Catalyst
Dong, Wenjie
Shen, Zheng
Peng, Boyu
Gu, Minyan
Zhou, Xuefei
Xiang, Bo
Zhang, Yalei
[J]. SCIENTIFIC REPORTS, 2016, 6
[10] DETERMINATION OF INTEGRATED MOLAR EXTINCTION COEFFICIENTS FOR INFRARED-ABSORPTION BANDS OF PYRIDINE ADSORBED ON SOLID ACID CATALYSTS
EMEIS, CA
[J]. JOURNAL OF CATALYSIS, 1993, 141 (02) : 347 - 354

← 1 2 3 4 →