A hierarchical supra-nanostructure of HKUST-1 featuring enhanced H2 adsorption enthalpy and higher mesoporosity

被引:50
作者
Du, Haiqiang [1 ]
Bai, Junfeng [1 ]
Zuo, Congyu [1 ]
Xin, Zhifeng [1 ]
Hu, Jinbo [1 ]
机构
[1] Nanjing Univ, State Key Lab Coordinat Chem, Nanjing Natl Lab Microstruct, Sch Chem & Chem Engn, Nanjing 210093, Peoples R China
关键词
METAL-ORGANIC FRAMEWORKS; POROUS COORDINATION POLYMER; HIGH-CAPACITY HYDROGEN; CU-BTC; HETEROGENEOUS CATALYSTS; GAS-ADSORPTION; CARBON-DIOXIDE; NANOCRYSTALS; SEPARATION; STORAGE;
D O I
10.1039/c1ce05124e
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A hierarchical supra-nanostructure of HKUST-1 was synthesized by directly mixing solutions of copper acetate and H3BTC (H3BTC = 1,3,5-benzenetricarboxylic acid) under ambient conditions, which exhibits enhanced H-2 adsorption enthalpy and higher mesoporosity.
引用
收藏
页码:3314 / 3316
页数:3
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