Spectral properties and thermal stability of Er3+-doped oxyfluoride silicate glasses for broadband optical amplifier

被引:118
作者
Xu, SQ [1 ]
Yang, ZM [1 ]
Dai, SX [1 ]
Yang, JH [1 ]
Hu, LL [1 ]
Jiang, ZH [1 ]
机构
[1] Chinese Acad Sci, Shanghai Inst Opt & Fine Mech, Shanghai 201800, Peoples R China
关键词
rare earth compounds; optical materials; thermal analysis; optical spectroscopy;
D O I
10.1016/S0925-8388(03)00447-X
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Er3+-doped 50SiO(2)-(50-x)PbO-xPbF(2) glasses were prepared. The effect of PbF2 content on refractive indices, densities, absorption spectra, the Judd-Ofelt parameters Omega(t) (t=2,4,6), fluorescence spectra and the lifetimes of I-4(13/2) level of Er3+ in 50SiO(2)-(50-x)PbO-xPbF(2) glasses were investigated, and the stimulated emission cross-section was calculated from McCumber theory. With increasing PbF2 content in the glass composition, the Omega(6) parameter, fluorescence full width at half maximum (FWHM) and lifetimes of I-4(13/2) level of Er3+ increase, while refractive indices and densities decrease. Compared with other glass hosts, the gain bandwidth properties of Er3+-doped 50SiO(2)-50PbF(2) glass is close to those of tellurite and bismuth glasses, and has an advantage over those of silicate, phosphate and germante glasses. The broad and flat I-4(13/2) --> I-4(15/2) emission of Er3+ around 1.55 mum can be used as host material for potential broadband optical amplifier in the wavelength-division-multiplexing (WDM) network system. (C) 2003 Elsevier B.V. All rights reserved.
引用
收藏
页码:313 / 319
页数:7
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