Fluorinated acrylic copolymers Part II: Polymeric surfactants

被引：18

作者：

Malshe, VC

Elango, S

Bhagwat, SS

Maghrabi, SS

机构：

[1] Univ Bombay, Inst Chem Technol, Paints & Polymer Technol Div, Bombay 400019, Maharashtra, India

[2] Univ Bombay, Inst Chem Technol, Div Chem Engn, Bombay 400019, Maharashtra, India

来源：

PROGRESS IN ORGANIC COATINGS | 2005年 / 53卷 / 03期

关键词：

fluorosurfactant; leveling agent; wetting agent; flow modifier;

D O I：

10.1016/j.porgcoat.2005.03.004

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

A novel series of water insoluble polymeric fluorosurfactants were synthesized by partial esterification of copolymers of hydroxy ethyl methacrylate (HEMA), methyl methacrylate (MMA), 2-ethyl hexyl acrylate (EHA) and butyl acrylate (BA) with tetrafluoro propanoic acid (TFPA) using PTSA as a catalyst and were characterized by IR. The molecular weight of the products was determined by GPC. Flow and wetting properties of these polymeric fluorosurfactants were evaluated in epoxy resins (liquid epoxy and solid epoxy), alkyd paint and powder coatings. Results showed that these polymeric fluorosurfactants could be used as wetting agent, flow additive in alkyd paint, epoxy resins and powder coatings with advantage. (c) 2005 Elsevier B.V. All rights reserved.

引用

页码：212 / 216

页数：5