Densities and viscosities of butyl acrylate plus 1-butanol and ethyl laurate plus 1-butanol at 293.15, 303.15, and 313.15 K

被引:46
作者
Liau, WR [1 ]
Tang, M [1 ]
Chen, YP [1 ]
机构
[1] Natl Taiwan Univ, Dept Chem Engn, Taipei 10764, Taiwan
关键词
D O I
10.1021/je9800611
中图分类号
O414.1 [热力学];
学科分类号
摘要
Densities and viscosities of binary liquid mixtures of butyl acrylate + 1-butanol and ethyl laurate + 1-butanol are presented over the complete concentration range at (293.15, 303.15, and 313.15) K. The densities were measured using a vibrating tube digital densimeter, and the viscosities were measured by a capillary viscometer. Excess molar volumes and viscosity deviations were then calculated at various temperatures. All excess molar volumes are positive, indicating the effect of disruption of the hydrogen bonding between 1-butanol molecules. Excess molar volumes and viscosity deviations were correlated by the Redlich-Kister type equations. Optimally fitted parameters are presented, and the correlation results are in satisfactory agreement with the experimental data.
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页码:826 / 829
页数:4
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