Copolymers containing functional groups intrinsic to the active centers of serine hydrolases: Synthesis and evaluation of catalytic capability

被引：1

作者：

Lozinsky, V. I. ^{[1
]}

Zaborina, O. E. ^{[1
]}

Klimova, T. P. ^{[1
]}

Babushkina, T. A. ^{[1
]}

Kovaleva, A. S. ^{[2
]}

Boltukhina, E. V. ^{[2
]}

Chernyshev, V. P. ^{[2
]}

Burova, T. V. ^{[1
]}

Grinberg, N. V. ^{[1
]}

Grinberg, V. Ya. ^{[1
]}

Khokhlov, A. R. ^{[1
]}

机构：

[1] Russian Acad Sci, AN Nesmeyanov Organoelement Cpds Inst, Ul Vavilova 28, Moscow 119991, Russia

[2] AO Shchelkovo Agrokhim, Zavodskaya Ul 2, Shchelkovo 141101, Moscow Oblast, Russia

来源：

POLYMER SCIENCE SERIES B | 2016年 / 58卷 / 01期

关键词：

CONFORMATION-DEPENDENT DESIGN; PROTEIN-LIKE COPOLYMERS; N-VINYLCAPROLACTAM POLYMERS; VINYLIMIDAZOLE COPOLYMERS; TRANSITIONS; ENERGETICS; BEHAVIOR;

D O I：

10.1134/S156009041601005X

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

N-Acryloyl derivatives of histamine, monoethanolamine, and beta-alanine, which contain imidazole, hydroxyl, and carboxyl functional groups, respectively, are synthesized and characterized. Copolymers, which are further divided into thermally precipitable and thermally nonprecipitable (soluble) fractions, are obtained via the free-radical copolymerization of N-vinylcaprolactam and the specified comonomers that is initiated by a persulfate-tertiary amine redox system in a medium of 10% aqueous dimethyl sulfoxide (DMSO) at 65A degrees C. It is shown that the soluble fractions of the synthesized copolymers exhibit catalytic activity in the reaction of hydrolysis of 4-nitrophenyl propionate (NPP) at a temperature above the coil-to-globule transition.

引用

页码：27 / 37

页数：11

共 25 条

[1] Copolymers containing functional groups intrinsic to the active centers of serine hydrolases: Synthesis and evaluation of catalytic capability
V. I. Lozinsky
O. E. Zaborina
T. P. Klimova
T. A. Babushkina
A. S. Kovaleva
E. V. Boltukhina
V. P. Chernyshev
T. V. Burova
N. V. Grinberg
V. Ya. Grinberg
A. R. Khokhlov
Polymer Science Series B, 2016, 58 : 27 - 37
[2] SYNTHESIS AND CATALYTIC ACTIVITY OF OPTICALLY-ACTIVE POLYMERS CONTAINING OXIME GROUPS
AGLIETTO, M
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POLYMER, 1980, 21 (05) : 541 - 544
[3] Synthesis and characterization of polyimide-polyoxyethylene copolymers containing carboxylic acid functional groups
Rao, BS
EUROPEAN POLYMER JOURNAL, 1997, 33 (09) : 1529 - 1536
[4] Synthesis of diblock copolymers by end functional polystyrene containing phenylseleno groups as polymeric photoiniferter
Kwon, TS
Takagi, K
Kunisada, H
Yuki, Y
JOURNAL OF MACROMOLECULAR SCIENCE-PURE AND APPLIED CHEMISTRY, 2002, A39 (09): : 991 - 1006
[5] RAFT synthesis of acrylic copolymers containing poly(ethylene glycol) and dioxolane functional groups: Toward well-defined aldehyde containing copolymers for bioconjugation
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Zou, Yuquan
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MACROMOLECULES, 2008, 41 (14) : 5272 - 5282
[6] SYNTHESIS AND CATALYTIC PROPERTIES OF PEPTIDES CONTAINING AMINO-ACIDS INVOLVED IN ACTIVE-CENTERS OF HYDROLYTIC ENZYMES
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SAKARELLOUDAITSIOTOU, M
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1976, (06): : 589 - 591
[7] Synthesis and self-assembly behavior of pH-responsive amphiphilic copolymers containing ketal functional groups
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Zhang, Hao
Nie, Jun
Yang, Jing
POLYMER INTERNATIONAL, 2010, 59 (07) : 967 - 974
[8] Synthesis of poly(arylene ether) copolymers containing pendant PEO groups and evaluation of their blends as proton conductive membranes
Deimede, VA
Kallitsis, JK
MACROMOLECULES, 2005, 38 (23) : 9594 - 9601
[9] MULTIFUNCTIONAL HYDROLYTIC CATALYZES .4. CATALYTIC HYDROLYSIS OF PARA-NITROPHENYL ACETATE BY COPOLYMERS CONTAINING COMPLEMENTARY FUNCTIONAL GROUPS (HYDROXAMATE AND IMIDAZOLE)
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MACROMOLECULES, 1976, 9 (01) : 15 - 22
[10] Synthesis, characterization and catalytic activity of ordered SBA-15 materials containing high loading of diamine functional groups
Wang, Xueguang
Chan, Jerry C. C.
Tseng, Yao-Hung
Cheng, Soofin
MICROPOROUS AND MESOPOROUS MATERIALS, 2006, 95 (1-3) : 57 - 65

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