1-(Diphenylphosphinothioyl)-2-[(4-methylphenyl)methoxymethyl]ferrocene

被引：1
|
作者：
Daran, Jean-Claude [1 ]
Audin, Catherine [2 ]
Deydier, Eric [2 ]
Manoury, Eric [1 ]
Poli, Rinaldo [1 ]
机构：
[1] CNRS, Chim Coordinat Lab, UPR 8241, F-31077 Toulouse, France
[2] Univ Toulouse, Inst Univ Technol Paul Sabatier, Dept Chim, F-81104 Castres, France
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2010年 / 66卷
关键词：
DESYMMETRIZING HYDROFORMYLATION; LIGANDS; FERROCENE; PHOSPHINE; AID;
D O I：
10.1107/S1600536810040791
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
Following our continuing interest in developing new chiral phosphine-containing ferrocenyl ligands, we synthesized the title compound, [Fe(C5H5)(C26H24OPS)], in which there are two nearly identical molecules in the asymmetric unit. The conformation of the cyclopentadienyl (Cp) rings in each ferrocenyl group are intermediate between eclipsed and staggered, with twist angles of 16.6 (2) and 8.9 (2)degrees. The protecting S atom is located endo with respect to the substituted Cp ring. In the crystal, molecules are connected through intermolecular C-H center dot center dot center dot pi interactions.
引用
收藏
页码：M1417 / U750
页数：19
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