The promotion effect of Co doping on the K resistance of Mn/TiO2 catalyst for NH3-SCR of NO

被引:59
|
作者
Chen, Qi-lin [1 ,2 ]
Guo, Rui-tang [1 ,2 ]
Wang, Qing-shan [1 ,2 ]
Pan, Wei-guo [1 ,2 ]
Yang, Ning-zhi [1 ,2 ]
Lu, Chen-zi [1 ,2 ]
Wang, Shu-xian [1 ,2 ]
机构
[1] Shanghai Univ Elect Power, Sch Energy Source & Mech Engn, Shanghai, Peoples R China
[2] Shanghai Engn Res Ctr Power Generat Environm Prot, Shanghai, Peoples R China
基金
上海市自然科学基金; 中国国家自然科学基金;
关键词
Mn/TiO2; catalyst; Cobalt; Potassium; Resistance; Characterization; LOW-TEMPERATURE SCR; MANGANESE OXIDES; CARBON NANOTUBES; NITROGEN-OXIDES; SELECTIVE REDUCTION; MODIFIED MNOX/TIO2; SUPERIOR CATALYST; NITRIC-OXIDE; NH3; DEACTIVATION;
D O I
10.1016/j.jtice.2016.03.045
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
In this study, it was found that the doping of Co on Mn/TiO2 catalyst could enhance its K resistance. The characterization results showed that the modification of Mn/TiO2 catalyst by Co could increase its reducibility and the adsorption of NH3 and NOx species on it. From the results of in situ DRIFT study, the NH3-SCR reaction over Mn/TiO2 catalyst obeyed the Langmuir-Hinshelwood mechanism. And the addition of K on Mn-Co/TiO2 had little inhibition effect on NOx adsorption. These features made Mn-Co/TiO2 catalyst show better K resistance than Mn/TiO2. (C) 2016 Taiwan Institute of Chemical Engineers. Published by Elsevier B.V. All rights reserved.
引用
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页码:116 / 123
页数:8
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