Simple and efficient AuI-based catalyst for hydroamination of alkynes

被引：11

作者：

Anokhin, Maksim V. ^{[1
]}

Murashkina, Anna V. ^{[1
]}

Averin, Alexei D. ^{[1
]}

Beletskaya, Irina P. ^{[1
]}

机构：

[1] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119991, Russia

来源：

MENDELEEV COMMUNICATIONS | 2014年 / 24卷 / 06期

基金：

俄罗斯科学基金会;

关键词：

INTERMOLECULAR HYDROAMINATION; REDUCTIVE AMINATION; ASYMMETRIC HYDROGENATION; HIGHLY EFFICIENT; GOLD(I) COMPLEX; ALKENES; ALLENES;

D O I：

10.1016/j.mencom.2014.11.004

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Hydroamination of terminal alkynes with anilines in the presence of (C6F5)(3)PAuNTf2 catalyst affords 2-aryliminoalkanes whose reduction in situ with sodium borohydride gives the corresponding secondary amines in high yields.

引用

页码：332 / 333

页数：2

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