Simple and efficient AuI-based catalyst for hydroamination of alkynes

被引：11

作者：

Anokhin, Maksim V. ^{[1
]}

Murashkina, Anna V. ^{[1
]}

Averin, Alexei D. ^{[1
]}

Beletskaya, Irina P. ^{[1
]}

机构：

[1] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119991, Russia

来源：

MENDELEEV COMMUNICATIONS | 2014年 / 24卷 / 06期

基金：

俄罗斯科学基金会;

关键词：

INTERMOLECULAR HYDROAMINATION; REDUCTIVE AMINATION; ASYMMETRIC HYDROGENATION; HIGHLY EFFICIENT; GOLD(I) COMPLEX; ALKENES; ALLENES;

D O I：

10.1016/j.mencom.2014.11.004

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Hydroamination of terminal alkynes with anilines in the presence of (C6F5)(3)PAuNTf2 catalyst affords 2-aryliminoalkanes whose reduction in situ with sodium borohydride gives the corresponding secondary amines in high yields.

引用

页码：332 / 333

页数：2

共 26 条

[1] Transition-metal-catalyzed addition of heteroatom-hydrogen bonds to alkynes [J].

Alonso, F ;

Beletskaya, IP ;

Yus, M .

CHEMICAL REVIEWS, 2004, 104 (06) :3079-3159

[2] Molecular approaches to catalysis Naked gold nanoparticles as quasi-molecular catalysts for green processes [J].

Boronat, Mercedes ;

Corma, Avelino .

JOURNAL OF CATALYSIS, 2011, 284 (02) :138-147

[3]

Corma A., 2006, NATURE, V313, P332

[4] Gold supported on a biopolymer (chitosan) catalyzes the regioselective hydroamination of alkynes [J].

Corma, Avelino ;

Concepcion, Patricia ;

Dominguez, Irene ;

Fornes, Vicente ;

Sabater, Maria J. .

JOURNAL OF CATALYSIS, 2007, 251 (01) :39-47

[5] Selective oxidation using gold [J].

Della Pina, Cristina ;

Falletta, Ermelinda ;

Prati, Laura ;

Rossi, Michele .

CHEMICAL SOCIETY REVIEWS, 2008, 37 (09) :2077-2095

[6] Asymmetric hydrogenation of imines with a recyclable chiral frustrated Lewis pair catalyst [J].

Ghattas, Ghazi ;

Chen, Dianjun ;

Pan, Fangfang ;

Klankermayer, Juergen .

DALTON TRANSACTIONS, 2012, 41 (30) :9026-9028

[7] Gold versus Silver-Catalyzed Intermolecular Hydroaminations of Alkenes and Dienes [J].

Giner, Xavier ;

Najera, Carmen ;

Kovacs, Gabor ;

Lledos, Agusti ;

Ujaque, Gregori .

ADVANCED SYNTHESIS & CATALYSIS, 2011, 353 (18) :3451-3466

[8] Identification of active gold nanoclusters on iron oxide supports for CO oxidation [J].

Herzing, Andrew A. ;

Kiely, Christopher J. ;

Carley, Albert F. ;

Landon, Philip ;

Hutchings, Graham J. .

SCIENCE, 2008, 321 (5894) :1331-1335

[9] Au(I)-catalyzed cyclization of tert-butyl carbonates derived from homopropargyl alcohols:: A catalytic alternative to cyclic enol carbonates [J].

Kang, JE ;

Shin, S .

SYNLETT, 2006, (05) :717-720

[10] Homogeneous catalytic hydroamination of alkynes and allenes with ammonia [J].

Lavallo, Vincent ;

Frey, Guido D. ;

Donnadieu, Bruno ;

Soleilhavoup, Michele ;

Bertrand, Guy .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (28) :5224-5228

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