Synthesis and Characterization of Chlorine-Containing Flame-Retardant Polyurethane Nanocomposites via In Situ Polymerization

We have developed flame-retardant polyurethanes (FRPUs) and polyurethane (PU) nanocomposites via in situ polymerization. Three series of thermoplastic elastomeric PUs were synthesized to investigate the effect of incorporating 3-chloro-1,2-propanediol (CPD) and nanoclay on mechanical, thermal properties, and also resistance to burning. PU soft segments were based on poly(propylene glycol). Hard segments were based on either CPD or 1,4-buthane diol (BDO) in combination with methyl phenyl di-isocyanate named PU or FRPU, respectively. In the third series, CPD was used as chain extender also nanoclay (1% wt) and incorporated and named as flame-retardant polyurethane nanocomposites (FRPUN). Mechanical properties and LOI of PUs and nanocomposites have been evaluated. Results showed that increasing the hard segment (chlorine content) leads to the increase in flame retardancy and burning time. Addition of nanoclay to CPD-containing PUs leads to obtain self-extinguish PUs using lower CPD contents, higher Young's modulus, and strength without any noticeable decrease in elongation at break. Investigation of the TGA results showed that copresence of nanoclay and chlorine structure in the PU backbone can change thermal degradation pattern and improve nanocomposite thermal stability. X-ray diffraction and transmission electron microscopy studies confirmed that exfoliation and intercalation have been well done. (C) 2011 Wiley Periodicals, Inc. J Appl Polym Sci 123: 437-447, 2012