Phase Equilibria of Three Binary Mixtures: Methanethiol plus Methane, Methanethiol plus Nitrogen, and Methanethiol plus Carbon Dioxide

被引：12

作者：

Awan, Javeed A. ^{[1
]}

Tsivintzelis, Ioannis ^{[1
]}

Coquelet, Christophe ^{[2
]}

Kontogeorgis, Georgios M. ^{[1
]}

机构：

[1] Tech Univ Denmark, Dept Chem & Biochem Engn, Ctr Energy Resources Engn, DK-2800 Lyngby, Denmark

[2] MINES ParisTech, CEP TEP Ctr Energet & Proc, F-77305 Fontainebleau, France

来源：

JOURNAL OF CHEMICAL AND ENGINEERING DATA | 2012年 / 57卷 / 03期

关键词：

EQUATION-OF-STATE;

D O I：

10.1021/je2011049

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

New vapor-liquid equilibrium (VLE) data for methanethiol (MM) + methane (CH4), methanethiol (MM) + nitrogen (N-2), and methanethiol (MM) + carbon dioxide (CO2) is reported for temperatures of (304, 334, and 364) K in the pressure range (1 to 8) MPa. A "static-analytic" method was used for performing the measurements. The objective is to provide experimental VLE data for methanethiol with other natural gas contents at its crude form, for which no data are available in the open literature. The new VLE data for the aforementioned systems have been modeled successfully with the cubic-plus-association equation of state (CPA EoS).

引用

页码：896 / 901

页数：6

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