High and robust performance of H2O2 fuel cells in the presence of scandium ion

被引:138
作者
Yamada, Yusuke [1 ,2 ,3 ]
Yoneda, Masaki [1 ,2 ]
Fukuzumi, Shunichi [1 ,2 ,3 ,4 ,5 ,6 ,7 ]
机构
[1] Osaka Univ, Grad Sch Engn, Div Adv Sci & Biotechnol, Dept Mat & Life Sci,ALCA, Suita, Osaka 5650871, Japan
[2] Japan Sci & Technol, SENTAN, Suita, Osaka 5650871, Japan
[3] Osaka City Univ, Grad Sch Engn, Dept Appl Chem & Bioengn, Sumiyoshi Ku, Osaka 5588585, Japan
[4] Ewha Womans Univ, Dept Bioinspired Sci, Seoul 120750, South Korea
[5] Meijo Univ, Fac Sci & Technol, Tempaku Ku, Nagoya, Aichi 4688502, Japan
[6] ALCA, Tempaku Ku, Nagoya, Aichi 4688502, Japan
[7] SENTAN, Tempaku Ku, Nagoya, Aichi 4688502, Japan
基金
日本科学技术振兴机构; 日本学术振兴会;
关键词
HYDROGEN-PEROXIDE PRODUCTION; CARBON-FIBER CLOTH; 2-ELECTRON REDUCTION; ESR-SPECTRA; SOLAR FUELS; CATHODE; COMPLEXES; DIOXYGEN; WATER; ELECTROREDUCTION;
D O I
10.1039/c5ee00748h
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Performance of an H2O2 fuel cell employing an Ni mesh and [Fe-II(H2O)(2)](3)[Co-III(CN)(6)](2) as an anode and a cathode, respectively, was remarkably enhanced in terms of open circuit potential, power density, and durability by the addition of Sc3+ ion to an aqueous H2O2 fuel.
引用
收藏
页码:1698 / 1701
页数:4
相关论文
共 40 条
[1]   Performance of an alkaline direct ethanol fuel cell with hydrogen peroxide as oxidant [J].
An, L. ;
Zhao, T. S. ;
Zeng, L. ;
Yan, X. H. .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2014, 39 (05) :2320-2324
[2]   The dual role of hydrogen peroxide in fuel cells [J].
An, Liang ;
Zhao, Tianshou ;
Yan, Xiaohui ;
Zhou, Xuelong ;
Tan, Peng .
SCIENCE BULLETIN, 2015, 60 (01) :55-64
[3]   Solar fuels generation and molecular systems: is it homogeneous or heterogeneous catalysis? [J].
Artero, Vincent ;
Fontecave, Marc .
CHEMICAL SOCIETY REVIEWS, 2013, 42 (06) :2338-2356
[4]   Molecular artificial photosynthesis [J].
Berardi, Serena ;
Drouet, Samuel ;
Francas, Laia ;
Gimbert-Surinach, Carolina ;
Guttentag, Miguel ;
Richmond, Craig ;
Stoll, Thibaut ;
Llobet, Antoni .
CHEMICAL SOCIETY REVIEWS, 2014, 43 (22) :7501-7519
[5]   A study of cathode catalysis for the aluminium hydrogen peroxide semi-fuel cell [J].
Bessette, RR ;
Cichon, JM ;
Dischert, DW ;
Dow, EG .
JOURNAL OF POWER SOURCES, 1999, 80 (1-2) :248-253
[6]   Energy storage using aqueous hydrogen peroxide [J].
Disselkamp, Robert S. .
ENERGY & FUELS, 2008, 22 (04) :2771-2774
[7]  
Fukuzumi S, 2000, CHEM-EUR J, V6, P4532, DOI 10.1002/1521-3765(20001215)6:24<4532::AID-CHEM4532>3.0.CO
[8]  
2-9
[9]   ESR spectra of superoxide anion-scandium complexes detectable in fluid solution [J].
Fukuzumi, S ;
Patz, M ;
Suenobu, T ;
Kuwahara, Y ;
Itoh, S .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (07) :1605-1606
[10]   Shape- and Size-Controlled Nanomaterials for Artificial Photosynthesis [J].
Fukuzumi, Shunichi ;
Yamada, Yusuke .
CHEMSUSCHEM, 2013, 6 (10) :1834-1847