Ferrocenecarbothioamide and N-ethoxycarbonylferrocenecarbothioamide:: Synthesis, structure and application in synthesis of 2,4-diferrocenylthiazole

被引：16
|
作者：
Plazuk, D
Zakrzewski, J
Rybarczyk-Pirek, A
Domagala, S
机构：
[1] Univ Lodz, Dept Organ Chem, PL-90136 Lodz, Poland
[2] Univ Lodz, Dept Crystallog, PL-90136 Lodz, Poland
[3] Univ Lodz, Dept Inorgan & Gen Chem, PL-90136 Lodz, Poland
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2005年 / 690卷 / 19期
关键词：
ferrocene; thioamide; Friedel-Crafts reaction; chloroacetylferrocene; thiazole;
D O I：
10.1016/j.jorganchem.2005.06.037
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Ferrocenecarbothioamide (1) and its N-ethoxycarbonyl derivative (2) were synthesised by a Friedel-Crafts type reaction of ferrocene with potassium thiocyanate and ethoxycarbonyl isothiocyanate, respectively, in a strongly acidic medium. The X-ray structure of I was determined and shows conjugation between the ferrocene moiety and the thioamido group. Compound I reacts with chloroacetylferrocene affording 2,4-diferrocenylthiazole, whose structure was determined by X-ray diffraction and electronic properties studied by cyclic voltammetry. (c) 2005 Elsevier B.V. All rights reserved.
引用
收藏
页码：4302 / 4308
页数：7
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