Colorimetric detection of heavy metal ions in water via metal-organic framework

被引：17

作者：

Kim, Jiwon ^{[1
]}

Oh, Jung Suk ^{[1
]}

Park, Kyoung Chul ^{[1
]}

Gupta, Gajendra ^{[1
,2
]}

Lee, Chang Yeon ^{[1
,2
]}

机构：

[1] Incheon Natl Univ, Dept Energy & Chem Engn, Incheon 22012, South Korea

[2] Incheon Natl Univ, Innovat Ctr Chem Engn, Incheon 22012, South Korea

来源：

INORGANICA CHIMICA ACTA | 2019年 / 486卷

关键词：

Metal-organic frameworks; Solvent-assisted ligand incorporation; Heavy metal detection; Luminescent properties; LIGAND; EFFICIENT; MERCURY; PYRENE;

D O I：

10.1016/j.ica.2018.10.025

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Interest in the design and use of metal-organic frameworks (MOFs) for the selective detection of heavy metal ions is increasing rapidly. Herein, a new SALI-MAA-3eq MOF was synthesized by incorporating mercaptoacetic acid into NU-1000 via a solvent-assisted ligand incorporation (SALI) approach. SALI-MAA-3eq was fully characterized by common analytical techniques and further tested for sensing applications. SALI-MAA-3eq was found to selectively detect Hg2+ over a range of metal ions in an aqueous environment. Its selectivity was further confirmed by fluorescence and X-ray photoelectron spectroscopy (XPS) studies.

引用

页码：69 / 73

页数：5

共 20 条

[1]

Deria P, 2014, CHEM SOC REV, V43, P5896, DOI [10.1039/C4CS00067F, 10.1039/c4cs00067f]

[2] Perfluoroalkane Functionalization of NU-1000 via Solvent-Assisted Ligand Incorporation: Synthesis and CO2 Adsorption Studies [J].

Deria, Pravas ;

Mondloch, Joseph E. ;

Tylianakis, Emmanuel ;

Ghosh, Pritha ;

Bury, Wojciech ;

Snurr, Randall Q. ;

Hupp, Joseph T. ;

Farha, Omar K. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2013, 135 (45) :16801-16804

[3] Spectroscopic, computational modeling and cytotoxicity of a series of meso-phenyl and meso-thienyl-BODIPYs [J].

Gibbs, Jaime H. ;

Robins, Larry T. ;

Zhou, Zehua ;

Bobadova-Parvanova, Petia ;

Cottam, Michael ;

McCandless, Gregory T. ;

Fronczek, Frank R. ;

Vicente, M. Graca H. .

BIOORGANIC & MEDICINAL CHEMISTRY, 2013, 21 (18) :5770-5781

[4] A seleno-pyrene selective probe for Hg2+ detection in either aqueous or aprotic systems [J].

Goncalves, Augusto C. ;

Capelo, Jose Luis ;

Lodeiro, Carlos ;

Dos Santos, Alcindo A. .

SENSORS AND ACTUATORS B-CHEMICAL, 2017, 239 :311-318

[5] Current progress on understanding the impact of mercury on human health [J].

Ha, Eunhee ;

Basu, Niladri ;

Bose-O'Reilly, Stephan ;

Dorea, Jose G. ;

McSorley, Emeir ;

Sakamoto, Mineshi ;

Chan, Hing Man .

ENVIRONMENTAL RESEARCH, 2017, 152 :419-433

[6] Is low-level environmental mercury exposure of concern to human health? [J].

Holmes, P. ;

James, K. A. F. ;

Levy, L. S. .

SCIENCE OF THE TOTAL ENVIRONMENT, 2009, 408 (02) :171-182

[7]

Horcajada P, 2010, NAT MATER, V9, P172, DOI [10.1038/NMAT2608, 10.1038/nmat2608, 10.1038/NMAT260B]

[8] A review on the distribution of Hg in the environment and its human health impacts [J].

Kim, Ki-Hyun ;

Kabir, Ehsanul ;

Jahan, Shamin Ara .

JOURNAL OF HAZARDOUS MATERIALS, 2016, 306 :376-385

[9] Metal-Organic Framework Materials as Chemical Sensors [J].

Kreno, Lauren E. ;

Leong, Kirsty ;

Farha, Omar K. ;

Allendorf, Mark ;

Van Duyne, Richard P. ;

Hupp, Joseph T. .

CHEMICAL REVIEWS, 2012, 112 (02) :1105-1125

[10] Metal-organic framework materials as catalysts [J].

Lee, JeongYong ;

Farha, Omar K. ;

Roberts, John ;

Scheidt, Karl A. ;

Nguyen, SonBinh T. ;

Hupp, Joseph T. .

CHEMICAL SOCIETY REVIEWS, 2009, 38 (05) :1450-1459

← 1 2 →