Three-State Near-Infrared Electrochromism at the Molecular Scale

被引：87
作者：
Cui, Bin-Bin [1 ]
Zhong, Yu-Wu [1 ]
Yao, Jiannian [1 ]
机构：
[1] Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, CAS Key Lab Photochem, Beijing 100190, Peoples R China
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2015年 / 137卷 / 12期
基金：
中国国家自然科学基金;
关键词：
ELECTRON-TRANSFER; ELECTROPOLYMERIZED FILMS; VOLATILE MEMORY; MONOLAYERS; COMPLEXES; SURFACES; PLATFORM; DEVICES; LOGIC; ASSEMBLIES;
D O I：
10.1021/jacs.5b00586
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Self-assembled monolayer films of a cyclometalated ruthenium complex with a redox-active amine substituent and three carboxylic acid groups have been prepared on ITO electrode surfaces. The obtained thin films show three-state electrochromic switching with low electrochemical potential inputs and high near-infrared absorbance outputs. Thanks to the long retention time of each oxidation states, these films have been used to demonstrate surface-confined flip-flop memory functions with high ON/OFF ratios at the molecular scale.
引用
收藏
页码：4058 / 4061
页数：4
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