Change in the morphology of ZnO crystals by thermal evaporation method using a mixture of ZnS and graphite

被引:0
作者
Lee, Geun-Hyoung [1 ]
机构
[1] Dong Eui Univ, Elect & Elect Mat Engn, 176 Eomgwangno, Busan 47340, South Korea
关键词
Zinc sulfide; Graphite; Thermal evaporation; Zinc oxide crystals; Yo-yo like morphology; ZINC-OXIDE; NANOWIRE; GROWTH;
D O I
10.2109/jcersj2.17126
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
One dimensional rod-shaped and two dimensional twin-crystal shaped ZnO crystals were fabricated by thermal evaporation of a mixture of ZnS and graphite powders in air at atmospheric pressure. Twin-crystal shaped ZnO crystals were formed at 1050 degrees C, while rod-shaped ZnO crystals were synthesized at 1150 degrees C. The morphology of ZnO crystals was drastically changed according to the growth temperature. It is particularly interesting that two hexagonal plates formed a twin crystal, in which hexagonal shaped ZnO plates were symmetrically grown on both sides of a mirror-like plane. The twin crystal looked like a yo-yo. X-ray diffraction analysis showed that the rod and twin-crystal shaped ZnO crystals exhibited a wurtzite crystallographic structure. A strong green emission peak at 500nm was observed in the cathodoluminescence spectra of the ZnO crystals at room temperature. (C) 2017 The Ceramic Society of Japan. All rights reserved.
引用
收藏
页码:779 / 782
页数:4
相关论文
共 20 条
  • [1] [Anonymous], APPL PHYS LETT
  • [2] Field-effect transistors based on single semiconducting oxide nanobelts
    Arnold, MS
    Avouris, P
    Pan, ZW
    Wang, ZL
    [J]. JOURNAL OF PHYSICAL CHEMISTRY B, 2003, 107 (03) : 659 - 663
  • [3] Improved fill factors in amorphous silicon solar cells on zinc oxide by insertion of a germanium layer to block impurity incorporation
    Ganguly, G
    Carlson, DE
    Hegedus, SS
    Ryan, D
    Gordon, RG
    Pang, D
    Reedy, RC
    [J]. APPLIED PHYSICS LETTERS, 2004, 85 (03) : 479 - 481
  • [4] Two-dimensional micrometer-sized single-crystalline ZnO thin nanosheets
    Hu, JQ
    Bando, Y
    Zhan, JH
    Li, YB
    Sekiguchi, T
    [J]. APPLIED PHYSICS LETTERS, 2003, 83 (21) : 4414 - 4416
  • [5] Kim C., 2006, APPL PHYS LETT, V88
  • [6] Formation of double-side teethed nanocombs of ZnO and self-catalysis of Zn-terminated polar surface
    Lao, CS
    Gao, PM
    Sen Yang, R
    Zhang, Y
    Dai, Y
    Wang, ZL
    [J]. CHEMICAL PHYSICS LETTERS, 2006, 417 (4-6) : 358 - 362
  • [7] Lee Geun-Hyoung, 2012, [Journal of the Korean Institute of Electrical and Electronic Material Engineers, 전기전자재료학회논문지], V25, P110
  • [8] Changing the shape of ZnO nanostructures by controlling Zn vapor release: from tetrapod to bone-like nanorods
    Leung, YH
    Djurisic, AB
    Gao, J
    Xie, MH
    Chan, WK
    [J]. CHEMICAL PHYSICS LETTERS, 2004, 385 (1-2) : 155 - 159
  • [9] ZnO tetrapod nanocrystals
    Newton, Marcus C.
    Warburton, Pau A.
    [J]. MATERIALS TODAY, 2007, 10 (05) : 50 - 54
  • [10] Complex and oriented ZnO nanostructures
    Tian, ZRR
    Voigt, JA
    Liu, J
    McKenzie, B
    McDermott, MJ
    Rodriguez, MA
    Konishi, H
    Xu, HF
    [J]. NATURE MATERIALS, 2003, 2 (12) : 821 - 826