Recent topics of phosphine-mediated reactions

被引:51
作者
Karanam, Praneeth [1 ]
Reddy, Ganapuram Madhusudhan [1 ]
Koppolu, Srinivasa Rao [1 ]
Lin, Wenwei [1 ]
机构
[1] Natl Taiwan Normal Univ, Dept Chem, 88,Sec 4,Tingchow Rd, Taipei 11677, Taiwan
关键词
Phosphine-mediated reactions; Wittig reactions; Kukhtin-Ramirez adducts; Huisgen zwitterions; Annulations; INTRAMOLECULAR WITTIG REACTIONS; BOND-FORMING REACTIONS; ONE-POT SYNTHESIS; DIASTEREOSELECTIVE SYNTHESIS; CHEMOSELECTIVE SYNTHESIS; MULTIFUNCTIONAL ALKENES; TETRASUBSTITUTED FURANS; HUISGEN ZWITTERIONS; ANNULATION REACTION; 3-ALKYL ALLENOATES;
D O I
10.1016/j.tetlet.2017.11.051
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Phosphines constitute key organophosphorus reagents that are being widely used in industry as well as in research laboratories since over a century. Specifically, in last two decades, there have been numerous reports on phosphine-mediated and phosphine-catalyzed reactions. In terms of industrial application, phosphine-mediated reactions have received much attention when compared to the catalytic versions for the synthesis of a variety of structurally diverse organic frameworks. In this digest review, we wish to summarize the recent advances (2014-2017) in phosphine-mediated reactions that are primarily based on stoichiometric application of phosphine. (C) 2017 Elsevier Ltd. All rights reserved.
引用
收藏
页码:59 / 76
页数:18
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