Photo- and electroluminescence in a series of PPV type terpolymers containing fluorene, thiophene and phenylene units

被引:9
作者
Nowacki, Bruno [1 ]
Grova, Isabel R. [1 ]
Domingues, Raquel A. [2 ]
Faria, Gregorio C. [3 ]
Atvars, Teresa D. Z. [2 ]
Akcelrud, Leni [1 ]
机构
[1] Univ Fed Parana, Paulo Scarpa Polymer Lab LaPPS, BR-81531990 Curitiba, Parana, Brazil
[2] State Univ Campinas Unicamp, Inst Chem, BR-13084971 Campinas, SP, Brazil
[3] Univ Sao Paulo, Phys Inst Sao Carlos IFSC, BR-13560970 Sao Carlos, SP, Brazil
关键词
Fluorene; Phenylene; Thiophene; Conjugated copolymers; Photoluminescence; Electroluminescence; LIGHT-EMITTING-DIODES; ENERGY-TRANSFER; EMISSION PROPERTIES; CONJUGATED POLYMER; DE-AGGREGATION; COPOLYMER; DYNAMICS; LUMINESCENCE; DONOR; FILMS;
D O I
10.1016/j.jphotochem.2012.03.022
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The emissive properties of terpolymers with fluorene, thiophene and phenylene groups, forming alternating PPV type structures, are discussed in terms of their composition, photo- and electroluminescence properties. The fluorene groups were inserted in each phenylene-vinylene and thiophene-vinylene units, and their concentration did not vary, representing 50% of the molar composition. The ratio of thiophene-vinylene/phenylene-vinylene varied in the range 25,50 and 75%. Photo- and electroluminescence properties were strongly dependent on the thiophene-vinylene content and were compared with the fluorene-vinylene-thiophene and fluorene-vinylene-phenylene parent copolymers. (C) 2012 Elsevier B.V. All rights reserved.
引用
收藏
页码:71 / 79
页数:9
相关论文
共 49 条
  • [21] Photoluminescence dynamics of thiophene/phenylene co-oligomer thin films based on Forster energy transfer
    Hiramatsu, Toru
    Shimada, Takayuki
    Hotta, Shu
    Yanagi, Hisao
    [J]. THIN SOLID FILMS, 2008, 516 (09) : 2700 - 2703
  • [22] Solvent Dependent Assembly of a Polyfluorene-Polythiophene "Rod-Rod" Block Copolyelectrolyte: Influence on Photophysical Properties
    Knaapila, M.
    Evans, R. C.
    Gutacker, A.
    Garamus, V. M.
    Torkkeli, M.
    Adamczyk, S.
    Forster, M.
    Scherf, U.
    Burrows, H. D.
    [J]. LANGMUIR, 2010, 26 (07) : 5056 - 5066
  • [23] Krebs F., 2008, POLYM PHOTOVOLTAICS
  • [24] Polyfluorene terpolymers containing phenothiazine and fluorenone: Effects of donor and acceptor moieties on energy and intrachain charge transfer processes in the photoluminescence and electroluminescence of multichromophore copolymers
    Kulkarni, Abhishek P.
    Kong, Xiangxing
    Jenekhe, Samson A.
    [J]. MACROMOLECULES, 2006, 39 (25) : 8699 - 8711
  • [25] Precise Synthesis of Poly(fluorene-2,7-vinylene)s Containing Oligo(thiophene)s at the Chain Ends: Unique Emission Properties by the End Functionalization
    Kuwabara, Shingo
    Yamamoto, Nobuhiro
    Sharma, Prabhuodeyara M. Veeresha
    Takamizu, Kenji
    Fujiki, Michiya
    Geerts, Yves
    Nomura, Kotohiro
    [J]. MACROMOLECULES, 2011, 44 (10) : 3705 - 3711
  • [26] Molecular structure-property engineering for photovoltaic applications: Fluorene-acceptor alternating conjugated copolymers with varied bridged moieties
    Li, Yaowen
    Li, Hui
    Xu, Bin
    Li, Zaifang
    Chen, Feipeng
    Feng, Dongqing
    Zhang, Jibo
    Tian, Wenjing
    [J]. POLYMER, 2010, 51 (08) : 1786 - 1795
  • [27] Synthesis and photophysical study of a conjugated-non-conjugated oligoazomethine
    Machado, A. M.
    Da Motta Neto, J. D.
    Atvars, T. D. Z.
    Akcelrud, L.
    [J]. JOURNAL OF LUMINESCENCE, 2009, 129 (07) : 720 - 728
  • [28] Synthesis and electroluminescent properties of soluble poly(3,6-fluorene) and its copolymer
    Mo, Yueqi
    Jiang, Xi
    Cao, Derong
    [J]. ORGANIC LETTERS, 2007, 9 (21) : 4371 - 4373
  • [29] Control of energy transfer in oriented conjugated polymer-mesoporous silica composites
    Nguyen, TQ
    Wu, JJ
    Doan, V
    Schwartz, BJ
    Tolbert, SH
    [J]. SCIENCE, 2000, 288 (5466) : 652 - 656
  • [30] Solid-state NMR characterization of a series of copolymers containing fluorene, phenylene and thiophene units
    Nowacki, Bruno
    DeAzevedo, Eduardo Ribeiro
    Akcelrud, Leni
    [J]. POLYMER TESTING, 2011, 30 (03) : 342 - 347