Photo- and electroluminescence in a series of PPV type terpolymers containing fluorene, thiophene and phenylene units

被引:9
作者
Nowacki, Bruno [1 ]
Grova, Isabel R. [1 ]
Domingues, Raquel A. [2 ]
Faria, Gregorio C. [3 ]
Atvars, Teresa D. Z. [2 ]
Akcelrud, Leni [1 ]
机构
[1] Univ Fed Parana, Paulo Scarpa Polymer Lab LaPPS, BR-81531990 Curitiba, Parana, Brazil
[2] State Univ Campinas Unicamp, Inst Chem, BR-13084971 Campinas, SP, Brazil
[3] Univ Sao Paulo, Phys Inst Sao Carlos IFSC, BR-13560970 Sao Carlos, SP, Brazil
关键词
Fluorene; Phenylene; Thiophene; Conjugated copolymers; Photoluminescence; Electroluminescence; LIGHT-EMITTING-DIODES; ENERGY-TRANSFER; EMISSION PROPERTIES; CONJUGATED POLYMER; DE-AGGREGATION; COPOLYMER; DYNAMICS; LUMINESCENCE; DONOR; FILMS;
D O I
10.1016/j.jphotochem.2012.03.022
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The emissive properties of terpolymers with fluorene, thiophene and phenylene groups, forming alternating PPV type structures, are discussed in terms of their composition, photo- and electroluminescence properties. The fluorene groups were inserted in each phenylene-vinylene and thiophene-vinylene units, and their concentration did not vary, representing 50% of the molar composition. The ratio of thiophene-vinylene/phenylene-vinylene varied in the range 25,50 and 75%. Photo- and electroluminescence properties were strongly dependent on the thiophene-vinylene content and were compared with the fluorene-vinylene-thiophene and fluorene-vinylene-phenylene parent copolymers. (C) 2012 Elsevier B.V. All rights reserved.
引用
收藏
页码:71 / 79
页数:9
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