Different two-dimensional metal-organic frameworks through ligand modification

被引:4
作者
Zhang, Jian [1 ,2 ,3 ]
Wang, Bin [2 ,3 ]
Li, Ming [1 ]
Zhao, Min-Jian [2 ,3 ]
Xie, Ya-Bo [2 ,3 ]
Li, Jian-Rong [2 ,3 ]
机构
[1] Qingdao Univ Sci & Technol, Coll Chem & Mol Engn, State Key Lab Base Ecochem Engn, Qingdao, Peoples R China
[2] Beijing Univ Technol, Dept Chem & Chem Engn, Coll Environm & Energy Engn, Beijing, Peoples R China
[3] Beijing Univ Technol, Beijing Key Lab Green Catalysis & Separat, Coll Environm & Energy Engn, Beijing, Peoples R China
关键词
Metal-organic frameworks; ligand modification; crystal structure; topology; BUILDING UNITS; RETICULAR SYNTHESIS; SELECTIVE DETECTION; ACID; EXPLOSIVES; HYDROGEN; LINKERS; STORAGE;
D O I
10.1080/00958972.2016.1196291
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Through ligand modification, we have replaced the central benzene ring of H2TDBA ([1,1': 3', 1.-terphenyl]-4,4.-dicarboxylicacid) with the pyridine structurally related ligand H2PDDA (4,4'-(pyridine-2,6-diyl) dibenzoic acid), which makes the central pyridine ring of H2PDDA more coplanar with two benzene rings on both sides of the ligand. The modification results in a dramatically different linkage configuration, thereby allowing structural changes to the metal-organic frameworks (MOFs). Two 2-D MOFs, [Cu(TDBA)(DMA)2].H2O (BUT-221, DMA = N,N-dimethylacetamide), and [Cu 3 (PDDA) 3 (DMA) 2 (H2O)].5H2O (BUT-223) have been synthesized through reactions of two ditopic carboxylate ligands with Cu(NO3)2.3H2O under solvothermal conditions, and characterized by single-crystal X-ray diffraction, powder X-ray diffraction, thermogravimetric analysis and infrared spectroscopy. Topological analysis shows that BUT-221 is a twofold parallel interpenetrating 44 2-D network with a skl topology, while BUT-223 is a 2-D network with a kgm topology.
引用
收藏
页码:2193 / 2199
页数:7
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