The Interplay of Hydrogen Bonding and Multiple Metal Binding - A New Cyclic Polyaminopolyalcohol Ligand as Building Block for the Construction of Microporous, Supramolecular Networks

被引：13

作者：

Merten, Guenter J. ^{[1
]}

Neis, Christian ^{[1
]}

Stucky, Stefan ^{[1
]}

Huch, Volker ^{[1
]}

Rentschler, Eva ^{[2
]}

Natter, Harald ^{[1
]}

Hempelmann, Rolf ^{[1
]}

Stoewe, Klaus ^{[1
]}

Hegetschweiler, Kaspar ^{[1
]}

机构：

[1] Univ Saarland, Fachbereich Chem, D-66041 Saarbrucken, Germany

[2] Johannes Gutenberg Univ Mainz, Inst Anorgan Chem, D-55128 Mainz, Germany

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2012年 / 01期

关键词：

Coordination modes; Bridging ligands; N; O ligands; Amino alcohols; Chelates; Hydrogen bonds; MAGNETIC-PROPERTIES; CU-II; CRYSTAL; CLUSTER;

D O I：

10.1002/ejic.201100914

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Cyclohexane-based polyaminopolyalcohols (PAPAs) such as 1,3-diamino-1,2,3-trideoxy-cis-inositol (daci) have been prepared by hydrogenation of suitable aromatic precursors. The pentanuclear complex [Cu-5(daci)(4)(H-(2)daci)(2)](SO4)(3)center dot 18H(2)O (C3) revealed antiferromagnetic and ferromagnetic interactions between the Cu-II centers with an S = 3/2 ground state. The microporous structure of C3 exhibited a dehydration/rehydration reaction with an entirely amorphous dehydrated phase at 150 degrees C and a completely reversible rehydration process at 30 degrees C. The potential of PAPA ligands for forming polynuclear complexes and supramolecular, hydrogen-bonded networks is discussed.

引用

页码：31 / 35

页数：5

共 9 条

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