A blue luminescence glass-ceramics of Eu2+ ions activated Li2O-BaO-B2O3

被引：7

作者：

Huang Yanlin ^{[1
,2
]}

Cho, Eunjin ^{[1
]}

Jang, Kiwan ^{[1
]}

Lee, Ho Sueb ^{[1
]}

Wang Xigang ^{[2
]}

Qin Dake ^{[2
]}

Jiang Chuanfang ^{[2
]}

机构：

[1] Changwon Natl Univ, Dept Phys, Chang Won 641773, South Korea

[2] Soochow Univ, Sch Mat Engn, Suzhou 215021, Peoples R China

来源：

JOURNAL OF RARE EARTHS | 2008年 / 26卷 / 02期

关键词：

glass-ceramics; europium; optical materials; luminescence; rare earths;

D O I：

10.1016/S1002-0721(08)60068-X

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

New blue luminescence glass-ceramic samples were prepared in air by annealing of the Eu3+-doped Li2O-BaO-B2O3 glass. The as-made glass samples only showed the sharp emission peaks assigned to the transitions of D-5(0)-F-7(j) (J=0, 1, 2, 3, 4) of Eu3+ ions. The glass-ceramic samples gave a strong and broad emission band peaking at about 382 ran ascribed to the 5d-4f transition of Eu2+ ions. The optical properties such as excitation and emission spectra, and the decay time of the Eu2+ ions were investigated in the glasses or the glass-ceramics samples. The X-ray diffraction pattern showed that LiBaB9O15 might be demonstrated to be the crystallites in the glass-ceramic, which contributed to the blue luminescence. SEM micrograph was investigated on the glass-ceramic samples obtained by crystallization of the glass matrix resulting in a mixture of poly-crystals.

引用

页码：215 / 219

页数：5