Dehydrogenative coupling of 2,2′-bipyridine:: hydrothermal synthesis and crystal structure of a novel polyoxovanadate decorated with the 2,2′;6′,2":6",2"′-quaterpyridine ligand

被引：46

作者：

Xiao, DR ^{[1
]}

Hou, Y ^{[1
]}

Wang, EB ^{[1
]}

Lü, J ^{[1
]}

Li, YG ^{[1
]}

Xu, L ^{[1
]}

Hu, CW ^{[1
]}

机构：

[1] NE Normal Univ, Inst Polyoxomet Chem, Dept Chem, Changchun 130024, Jilin, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2004年 / 7卷 / 03期

关键词：

hydrothermal synthesis; dehydrogenative coupling; crystal structure; polyoxovanadate;

D O I：

10.1016/j.inoche.2004.01.001

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A novel polyoxovanadate [{Ni(quaterpy)(H2O)}(2)V4O12](.)10H(2)O (1) (quaterpy - 2,2';6',2";6",2'"-quaterpyridine) has been hydrothermally synthesized and structurally characterized. The title compound consists of tetranuclear V4O124- clusters grafted with [Ni(quaterpy)(H2O)](2+) complex. Compound 1 represents the first polyoxometalate decorated with quaterpy ligand. (C) 2004 Published by Elsevier B.V.

引用

页码：437 / 439

页数：3

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