The Phase Relationships in the Sb-S-I System and Thermodynamic Properties of the SbSI

被引：7
作者：
Aliev, Ziya S. [1 ,2 ]
Musayeva, Sabina S. [3 ]
Babanly, Mahammad B. [4 ]
机构：
[1] Azerbaijan State Oil & Ind Univ, Azadlig Ave 20, Baku 1010, Azerbaijan
[2] ANAS, Inst Phys, Baku 1143, Azerbaijan
[3] Baku State Univ, Baku 1148, Azerbaijan
[4] ANAS, Inst Catalysis & Inorgan Chem, Baku 1143, Azerbaijan
来源：
JOURNAL OF PHASE EQUILIBRIA AND DIFFUSION | 2017年 / 38卷 / 06期
关键词：
antimony sulfide; antimony sulfur iodide; antimony triiodide; electromotive forces; phase diagram; thermodynamic functions; CRYSTAL-STRUCTURE; DIAGRAM; EQUILIBRIA; SCATTERING;
D O I：
10.1007/s11669-017-0601-4
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The phase relationships in the Sb-S-I ternary system were determined experimentally over entire concentration range by means of differential thermal analysis (DTA) and x-ray diffraction (XRD) techniques. Two quasi-binary, three isopleth sections, 300 K isothermal section and liquidus surface projection of the system were revised. The primary crystallization fields of all existing phases, the types and coordinates of all invariant and monovariant equilibria were determined. The electromotive force measurements (EMF) method was used to calculate the partial molar functions of antimony in alloys and the standard integral thermodynamic functions of SbSI.
引用
收藏
页码：887 / 896
页数：10
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