Two steps ethanolysis of castor oil using sulfuric acid as catalyst to produce motor oil

被引:15
作者
Agra, IB
Warnijati, S
Wiratni
机构
[1] Departement of Chemical Engineering, Faculty of Engineering, Gadjah Mada University, Yogyakarta
关键词
two steps alcoholysis; castor oil; sulfuric acid catalyst; ethanol; motor fuel;
D O I
10.1016/0960-1481(96)88454-0
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Mixture of castor oil and sulfurc acid was heated in a three neck flask to about 80 degrees C, and then boiling ethanol was introduced into the reactor. After 60 minutes of processing, the experiment was stop and the glycerine formed was separated and the oil left was realcoholyzed in the same way as the first step. From the study it was obvious that the first and second steps of alcoholysis followed first order reactions, and the rate constants were affected by the catalyst concentration exponentially. The one step procces for 120 minutes converted only 60% of the glyceride, while the two steps alcoholysis could reach 82% conversion in 120 minute total time. Except for its viscosity, the liquid product approached the specification of diesel oil.
引用
收藏
页码:1025 / 1028
页数:4
相关论文
共 6 条
[1]  
AGRA IB, 1988, NAT WORKSH REC BIOM, P105
[2]  
GRIFFIN RC, 1955, TECHNICAL METHODS AN, P107
[3]  
PURWANINGSIH IS, 1988, BPPS UGM, V1, P218
[4]  
WARNIJATI S, 1990, INT C EN ENV, V2, P301
[5]  
WARNIJATI S, 1994, 5 ASEAN EN C APR 25, P348
[6]  
WARNIJATI S, 1992, 2 WORLD REN EN C, V3, P1479