Eco-friendly finishing agent for cotton fabrics to improve flame retardant and antibacterial properties

被引:142
作者
El-Shafei, A. [1 ]
Al-Shemy, Mona [1 ]
Abou-Okeil, A. [1 ]
机构
[1] Natl Res Ctr, Text Res Div, Tahrir St, Cairo, Egypt
关键词
Chitosan phosphate; Cotton finishing; Flame retardant; Antibacterial; TiO2; nanoparticles; CHITOSAN; TEXTILES; NANOPARTICLES; PYROLYSIS; CELLULOSE; ACID;
D O I
10.1016/j.carbpol.2014.11.007
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
This research work deals with flame retardant and antibacterial finishing agent for cellulosic fabrics using TiO2 nanoparticles and chitosan phosphate. TiO2 nanoparticles were prepared by sol-gel method using titanium tetraisopropoxide. The size of TiO2 nanoparticles was characterized using transmission electron microscope (TEM). The application of nano TiO2 onto cellulosic fabrics (cotton 100%) was achieved in presence of polycarboxylic acid [1,2,3,4-butane tetracarboxylic acid (BTCA)] with sodium hypophosphite (SHP) as catalyst and chitosan phosphate through conventional pad-dry-cure method. The effect of the finishing on the physical properties, flammability and antibacterial properties of cross-linked fabrics are investigated. Thermal gravimetric analysis (TGA) was employed to investigate the thermal decomposition behaviour of the treated samples. Limited oxygen indexes (LOI) of the treated cotton fabrics were investigated. The treated cotton fabric also reveals excellent antibacterial properties. (C) 2014 Elsevier Ltd. All rights reserved.
引用
收藏
页码:83 / 90
页数:8
相关论文
共 38 条
[1]   Urea phosphate/β-cyclodextrin inclusion complex to enhance thermal behavior of cotton fabric [J].
Abou-Okeil, A. ;
El-Shafie, A. .
CARBOHYDRATE POLYMERS, 2011, 84 (01) :593-598
[2]   Chitosan phosphate induced better thermal characteristics to cotton fabric [J].
Abou-Okeil, A. ;
El-Shafie, A. ;
Hebeish, A. .
JOURNAL OF APPLIED POLYMER SCIENCE, 2007, 103 (03) :2021-2026
[3]  
Brandrub J., 1966, POLYM HDB
[4]   THE FLAME RETARDANCE OF A NATURAL POLYMER BY A SULFUR-ALUMINUM-BROMINE SYSTEM [J].
CULLIS, CF ;
HIRSCHLER, MM ;
KHATTAB, MAAM .
EUROPEAN POLYMER JOURNAL, 1984, 20 (06) :559-562
[5]   A novel technique for producing durable multifunctional textiles using nanocomposite coating [J].
Dastjerdi, Roya ;
Montazer, Majid ;
Shahsavan, Shadi .
COLLOIDS AND SURFACES B-BIOINTERFACES, 2010, 81 (01) :32-41
[6]   Investigating the production and properties of Ag/TiO2/PP antibacterial nanocomposite filament yarns [J].
Dastjerdi, Roya ;
Mojtahedi, M. R. M. ;
Shoshtari, A. M. ;
Khosroshahi, A. .
JOURNAL OF THE TEXTILE INSTITUTE, 2010, 101 (03) :204-213
[7]   A new method to stabilize nanoparticles on textile surfaces [J].
Dastjerdi, Roya ;
Montazer, Majid ;
Shahsavan, Shadi .
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2009, 345 (1-3) :202-210
[8]  
Dennis P, 2002, POLYM DEGRADATION ST, V77, P213
[9]   ZnO/carboxymethyl chitosan bionano-composite to impart antibacterial and UV protection for cotton fabric [J].
El Shafei, A. ;
Abou-Okeil, A. .
CARBOHYDRATE POLYMERS, 2011, 83 (02) :920-925
[10]  
George Reports A. E., 1992, CHITIN CHEM