Development of aligned-hemp yarn-reinforced green composites with soy protein resin: Effect of pH on mechanical and interfacial properties

Unidirectional hemp yarn-reinforced green composites were fabricated with soy protein concentrate (SPC) resin processed at various pH values. To preserve the yarn alignment during the fabrication of green composites, hemp yarn was wound onto a metal frame with slight tension and precured SPC resin was applied to the yarns. Effects of pH values on the tensile properties of the SPC resin and hemp yarn/SPC resin interfacial shear strength (IFSS) were investigated. Increasing pH of the SPC resin from 7 to 12 decreased its fracture stress and Young's modulus from 13.1 MPa and 357.5 MPa to 8.1 MPa and 156.2 MPa, respectively. At the same time fracture strain and moisture content increased from 31.5% and 15.65% to 53.4% and 19.30%, respectively, indicating resin plasticization. However, hemp yarn/SPC resin IFSS increased from 17.7 MPa at pH 7 up to 28.0 MPa at pH 10, after which it decreased. The fracture toughness of the composites increased up to pH of 10 but further increase in pH reduced the toughness. SEM photomicrographs showed fracture surfaces of hemp yarn-reinforced green composites that indicated better resin/fiber interaction at pH of 10 than 7 or 12. (C) 2011 Elsevier Ltd. All rights reserved.