Chloridotetrakis(1-ethyl-1H-imidazole-κN3)copper(II) chloride monohydrate

被引:7
作者
Liu, Fa-Qian [1 ]
Liu, Wen-Li [1 ]
Li, Wei [1 ]
Li, Rong-Xun [1 ]
Liu, Guang-Ye [1 ]
机构
[1] Qingdao Univ Sci & Technol, Key Lab Adv Mat, Qingdao 266042, Peoples R China
来源
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2007年 / 63卷
关键词
D O I
10.1107/S1600536807041864
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The title compound, [CuCl(C5H8N2)4]Cl·H2O, consists of a discrete [CuCl(Eim)4]+ cation (Eim is 1-ethyl-1H-imidazole), one Cl - anion and one water mol-ecule. The CuII ion adopts a distorted square-pyramidal geometry. The basal coordination positions are occupied by the N atoms of the Eim ligands and the apical position is occupied by a Cl- anion. In the crystal structure, ions and water mol-ecules form three-dimensional hydrogen-bond networks which stabilize the structure. © International Union of Crystallography 2007.
引用
收藏
页码:M2454 / U195
页数:12
相关论文
共 6 条
[1]  
[Anonymous], 2001, SMART VERS 5 628
[2]   ON ENANTIOMORPH-POLARITY ESTIMATION [J].
FLACK, HD .
ACTA CRYSTALLOGRAPHICA SECTION A, 1983, 39 (NOV) :876-881
[3]  
Jian FF, 2004, CHINESE J STRUC CHEM, V23, P979
[4]   Structures of pentakis-(imidazole)copper(II) hexafluoroarsenate monohydrate and chlorotetrakis-(imidazole)copper(II) chloride [J].
Otieno, T ;
Hatfield, MJ ;
Asher, SL ;
McMullin, AI ;
Patrick, BO ;
Parkin, S .
SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY, 2001, 31 (09) :1587-1598
[5]  
Sheldrick G.M., 2001, SHELXTL VERSION 5 0
[6]  
Sheldrick G. M. G. M., 2004, SADABS