Fabrication of Highly Ordered Ag/TiO2 Nanopore Array as a Self-Cleaning and Recycling SERS Substrate

Silver nanoparticles deposited on a titania nanopore array (Ag/TiO2 NPA) has been designed as a surface-enhanced Raman scattering (SERS) substrate for sensitive and recycling application of organic molecule detection. A TiO2 NPA was fabricated by a surface oxidization reaction of a titanium sheet by a double anodization process. A Ag/TiO2 NPA was then formed by depositing silver nanoparticles onto the TiO2 NPA by a cycling chemical reduction deposition process. The Ag/TiO2 NPA has a uniform mono-layer dispersion of Ag nanoparticles with a size of 30-50 nm on TiO2 nanopores with a diameter of 100-110 nm. The Ag/TiO2 NPA SERS substrate could facilitate interfacial adsorption of Rhodamine 6G (R6G), which achieves a sensitive detection limit of 10(-8) M R6G through SERS spectrum measurement. The Ag/TiO2 NPA SERS substrate achieves an analytical enhancement factor value of 2.6 x 10(5). The Ag/TiO2 NRA could promote the UV light-excited photocatalytic degradation reaction of R6G adsorbed on its surface which gives rise to a refreshed Ag/TiO2 NRA under UV irradiation for 60 min and accordingly behave as a self-cleaning and recycling SERS substrate. The Ag/TiO2 NPA exhibits a much higher R6G degradation reaction rate constant (0.05764 min(-1)) than the TiO2 NPA (0.02600 min(-1)), indicating its superior photocatalytic activity and self-cleaning activity. The refreshed Ag/TiO2 NPA was able to be recycled for the Raman detection of R6G, maintaining a high stability, reproducibility, and cyclability. The highly ordered Ag/TiO2 NPA with well controlled Ag nanoparticle dispersion and TiO2 nanopore shape could act as a suitable SERS substrate for recycling and self-cleaning application for stable and sensitive molecule detection.