On the doubts related to the local structure, magnetization and Griffiths phase of self-doped La1-xMnO3+δ manganites

被引:17
作者
Ulyanov, A. N. [1 ]
Pismenova, N. E. [1 ]
Yang, D. S. [2 ]
Levchenko, G. G. [1 ]
机构
[1] Natl Acad Sci, Donetsk Physicotech Inst, UA-83114 Donetsk, Ukraine
[2] Chungbuk Natl Univ, Dept Phys Educ, Cheongju 361763, South Korea
关键词
Self-doped manganites; Crystal structure; Magnetic properties; Griffiths-like phase; X=0.22;
D O I
10.1016/j.jallcom.2014.09.011
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Self-doped La1-xMnO3+delta manganites (x = 0.0, 0.05, 0.1, and 0.15) have been studied. Results for the x = 0.15 sample are in agreement with the suggestion that a part of manganese ions, being in a trivalent state, occupies a vacant A-site of the perovskite ABO(3) cell. Magnetic behavior of the samples above T-C exhibits Griffiths-like features. The observed Griffiths singularity is suggested to be due to strain accommodation caused by the vacancies in the A- and B-positions of the ABO(3) cell. (C) 2014 Elsevier B.V. All rights reserved.
引用
收藏
页码:607 / 608
页数:2
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