Size-controlled synthesis of MIL-101(Cr) nanoparticles with enhanced selectivity for CO2 over N2

被引：138

作者：

Jiang, Dongmei ^{[1
]}

Burrows, Andrew D. ^{[1
]}

Edler, Karen J. ^{[1
]}

机构：

[1] Univ Bath, Dept Chem, Bath BA2 AY, Avon, England

来源：

CRYSTENGCOMM | 2011年 / 13卷 / 23期

基金：

英国工程与自然科学研究理事会;

关键词：

METAL-ORGANIC FRAMEWORKS; NANOSCALE COORDINATION POLYMERS; CONTRAST AGENTS; NANOCRYSTALS; ADSORPTION; CATALYSIS; MOF-5;

D O I：

10.1039/c1ce06274c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Nanoparticles of MIL-101(Cr) have been fabricated using a hydrothermal method for the first time. The particle size can be controlled from 19 (4) nm to 84 (12) nm, by using a monocarboxylic acid as a mediator. These nano MIL-101(Cr) materials exhibit higher selectivities for CO2 over N-2 than bulk MIL-101(Cr).

引用

收藏

页码：6916 / 6919

页数：4

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