Organically templated inorganic/organic hybrid materials:: hydrothermal synthesis and structural characterization of [C4H12N2][In2(C2O4)(HPO4)3]•H2O

被引：55

作者：

Huang, YF

Lii, KH ^{[1
]}

机构：

[1] Acad Sinica, Inst Chem, Taipei 115, Taiwan

[2] Natl Cent Univ, Dept Chem, Chungli 320, Taiwan

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1998年 / 24期

关键词：

D O I：

10.1039/a807345g

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis and characterization of a novel inorganic/organic hybrid material is described; the 3-D framework consists of InO6 octahedra which are linked by inorganic phosphate and organic oxalate anions to generate intersecting tunnels in which piperazinium cations and water molecules reside.

引用

页码：4085 / 4086

页数：2

共 18 条

[1] ASSEMBLY OF PORPHYRIN BUILDING-BLOCKS INTO NETWORK STRUCTURES WITH LARGE CHANNELS
ABRAHAMS, BF
HOSKINS, BF
MICHAIL, DM
ROBSON, R
[J]. NATURE, 1994, 369 (6483) : 727 - 729
[2] Synthesis and structural characterization of a novel tin(II) phosphonate, Sn2(O3PCH3)(C2O4)
Adair, B
Natarajan, S
Cheetham, AK
[J]. JOURNAL OF MATERIALS CHEMISTRY, 1998, 8 (06) : 1477 - 1479
[3] BOND-VALENCE PARAMETERS OBTAINED FROM A SYSTEMATIC ANALYSIS OF THE INORGANIC CRYSTAL-STRUCTURE DATABASE
BROWN, ID
ALTERMATT, D
[J]. ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1985, 41 (AUG): : 244 - 247
[4] Hydrothermal synthesis, structure, and magnetic properties of a novel monodimensional iron phosphate: [FeF(HPO4)(2),N2C3H12,(H2O)(x)] (X approximate to 0.20) (ULM-14)
Cavellec, M
Riou, D
Greneche, JM
Ferey, G
[J]. INORGANIC CHEMISTRY, 1997, 36 (10) : 2187 - 2190
[5] Synthesis and crystal structure of the first organically templated layered indium phosphate [C5H5NH](+)[In(HPO4)(H2PO4)(2)](-)
Chippindale, AM
Brech, SJ
[J]. CHEMICAL COMMUNICATIONS, 1996, (24) : 2781 - 2782
[6] A 3-D organically templated mixed valence (Fe2+/Fe3+) iron phosphate with oxide-centered Fe4O(PO4)4 cubes: Hydrothermal synthesis, crystal structure, magnetic susceptibility, and Mossbauer spectroscopy of [H3NCH2CH2NH3](2)[Fe4O(PO4)(4)]center dot H2O
DeBord, JRD
Reiff, WM
Warren, CJ
Haushalter, RC
Zubieta, J
[J]. CHEMISTRY OF MATERIALS, 1997, 9 (09) : 1994 - 1998
[7] HYDROTHERMAL SYNTHESIS AND CRYSTAL-STRUCTURE OF H3NCH2CH2NH3[IN2(HPO4)4] - A NOVEL OCTAHEDRAL TETRAHEDRAL FRAMEWORK INDIUM PHOSPHATE WITH OCCLUDED ORGANIC CATIONS
DHINGRA, SS
HAUSHALTER, RC
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1993, (21) : 1665 - 1667
[8] SPONTANEOUS ASSEMBLY OF A HINGED COORDINATION NETWORK
GARDNER, GB
VENKATARAMAN, D
MOORE, JS
LEE, S
[J]. NATURE, 1995, 374 (6525) : 792 - 795
[9] Engineering coordination architecture by hydrothermal synthesis; Preparation, X-ray crystal structure and magnetic behaviour of the coordination solid [Mn-3{C6H3(CO2)(3)-1,3,5}(2)]
Gutschke, SOH
Molinier, M
Powell, AK
Winpenny, REP
Wood, PT
[J]. CHEMICAL COMMUNICATIONS, 1996, (07) : 823 - 824
[10] REDUCED MOLYBDENUM PHOSPHATES - OCTAHEDRAL TETRAHEDRAL FRAMEWORK SOLIDS WITH TUNNELS, CAGES, AND MICROPORES
HAUSHALTER, RC
MUNDI, LA
[J]. CHEMISTRY OF MATERIALS, 1992, 4 (01) : 31 - 48

← 1 2 →