Thermal Conductivity and Specific Heat Capacity of Dodecylbenzenesulfonic Acid-Doped Polyaniline Particles-Water Based Nanofluid

被引:30
作者
Chew, Tze Siong [1 ]
Daik, Rusli [1 ]
Hamid, Muhammad Azmi Abdul [2 ]
机构
[1] Univ Kebangsaan Malaysia, Sch Chem Sci & Food Technol, Fac Sci & Technol, Ukm Bangi Selangor 43600, Malaysia
[2] Univ Kebangsaan Malaysia, Fac Sci & Technol, Sch Appl Phys, Bangi Selangor 43600, Malaysia
关键词
MICELLE POLYMERIZATION; NANOPARTICLES; VISCOSITY; TIO2;
D O I
10.3390/polym7071221
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Nanofluid has attracted great attention due to its superior thermal properties. In this study, chemical oxidative polymerization of aniline was carried out in the presence of dodecylbenzenesulfonic acid (DBSA) as a dopant. Particles of DBSA-doped polyaniline (DBSA-doped PANI) with the size range of 15 to 50 nm were obtained, as indicated by transmission electron microscope (TEM). Results of ultra violet-visible (UV-Vis) absorption and Fourier transform infrared (FTIR) spectroscopies as well as thermogravimetric analysis showed that PANI nanoparticles were doped with DBSA molecules. The doping level found was 36.8%, as calculated from elemental analysis data. Thermal conductivity of water was enhanced by 5.4% when dispersed with 1.0 wt% of DBSA-PANI nanoparticles. Specific heat capacity of water-based nanofluids decreased with increasing amount of DBSA-PANI nanoparticles.
引用
收藏
页码:1221 / 1231
页数:11
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