Synthesis, Structure and Characterization of Three Metal Molybdate Hydrates: Fe(H2O)2(MoO4)2•H3O, NaCo2(MoO4)2(H3O2) and Mn2(MoO4)3•2H3O

被引：0

作者：

Yu Yang ^{[1
]}

Liu Dan ^{[1
]}

Hu Wei-wei ^{[1
]}

Li Jia ^{[1
]}

Peng Yu ^{[1
]}

Zhou Qi ^{[1
]}

Yang Fen ^{[1
]}

Li Guang-hua ^{[1
]}

Shi Zhan ^{[1
]}

Feng Shou-hua ^{[1
]}

机构：

[1] Jilin Univ, Coll Chem, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Peoples R China

来源：

CHEMICAL RESEARCH IN CHINESE UNIVERSITIES | 2012年 / 28卷 / 02期

基金：

中国国家自然科学基金;

关键词：

Mixed-solvent-thermal synthesis; Crystal structure; Transition metal molybdate; Magnetic property; CRYSTAL-STRUCTURE; ELECTRONIC-STRUCTURE; MAGNETIC-PROPERTIES; COBALT MOLYBDATE; MECHANISM; MOSSBAUER; BEHAVIOR; PROPANE; OXIDES; COMOO4;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Three metal molybdate hydrates, Fe(H2O)(2)(MoO4)(2)center dot H3O(FeMo), NaCo2(MoO4)(2)(H3O2)(CoMo) and Mn-2(MoO4)(3).2H(3)O(MnMo), were synthesized by the mixed-solvent-thermal methods and characterized by single-crystal X-ray diffraction. X-Ray photoelectron spectroscopy and bond-valence sums were applied to confirming the valance of Fe, Co, Mn and Mo. Thermo-gravimetric analysis and X-ray powder diffraction measurements indicate that the samples were converted to different structural compounds upon heating in air at 600 degrees C for 1 h. The magnetic properties of these compounds were studied. The dominant magnetic interactions are antiferromagnetic in nature. However, different synthesis conditions led to the diversity of magnetic properties of compound CoMo.

引用

页码：186 / 190

页数：5

共 34 条

[1] Electronic structure and optical properties of CdMoO4 and CdWO4
Abraham, Y
Holzwarth, NAW
Williams, RT
[J]. PHYSICAL REVIEW B, 2000, 62 (03): : 1733 - 1741
[2] Crystal Structure of the Transition-Metal Molybdates. I. Paramagnetic Alpha-MnMoO(4)
Abrahams, S. C.
Reddy, J. M.
[J]. JOURNAL OF CHEMICAL PHYSICS, 1965, 43 (07) : 2533 - 2543
[3] BOND-VALENCE PARAMETERS OBTAINED FROM A SYSTEMATIC ANALYSIS OF THE INORGANIC CRYSTAL-STRUCTURE DATABASE
BROWN, ID
ALTERMATT, D
[J]. ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1985, 41 (AUG): : 244 - 247
[4] Characterization of Mo-MnO catalyst for propane oxidative dehydrogenation
Cadus, LE
Ferretti, O
[J]. APPLIED CATALYSIS A-GENERAL, 2002, 233 (1-2) : 239 - 253
[5] COURTINE P, 1968, B SOC CHIM FR, P4816
[6] Cui B, 2007, CHEM J CHINESE U, V28, P1
[7] General synthesis and phase control of metal molybdate hydrates MMoO4•nH2O (M = Co, Ni, Mn, n=0, 3/4, 1) nano/microcrystals by a hydrothermal approach:: Magnetic, photocatalytic, and electrochemical properties
Ding, Yi
Wan, Yong
Min, Yu-Lin
Zhang, Wei
Yu, Shu-Hong
[J]. INORGANIC CHEMISTRY, 2008, 47 (17) : 7813 - 7823
[8] PREPARATION AND PROPERTIES OF TRANSITION METAL MOLYBDATES .6.
DOYLE, WP
MCGUIRE, G
CLARK, GM
[J]. JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1966, 28 (05): : 1185 - &
[9] Gao L, 2009, CHEM J CHINESE U, V30, P1691
[10] Promotion of the hydrogen peroxide decomposition activity of manganese oxide catalysts
Hasan, MA
Zaki, MI
Pasupulety, L
Kumari, K
[J]. APPLIED CATALYSIS A-GENERAL, 1999, 181 (01) : 171 - 179

← 1 2 3 4 →