Synthesis and highly diastereoselective palladation of (η5-(S)-2-(4-methylethyl)oxazolinylcyclopentadienyl)-(η4-tetraphenylcyclobutadiene)cobalt

被引：102

作者：

Stevens, AM ^{[1
]}

Richards, CJ ^{[1
]}

机构：

[1] Cardiff Univ, Dept Chem, Cardiff CF1 3TB, S Glam, Wales

来源：

ORGANOMETALLICS | 1999年 / 18卷 / 07期

关键词：

D O I：

10.1021/om980812s

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Starting from sodium carbomethoxycyclopentadienide, diphenylacetylene, and chlorotris(triphenylphosphine)cobalt(I), the title compound mas obtained in four steps and 47% overall yield. On reaction with Pd(OAc)(2), a single cyclopalladated diastereoisomer of (S)-(pR) configuration was isolated in 72% yield.

引用

页码：1346 / 1348

页数：3

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