High-spin molecules with magnetic anisotropy toward single-molecule magnets

High-spin molecules with easy-axis magnetic anisotropy show slow magnetic relaxation of spin-flipping along the axis of magnetic anisotropy and are called single-molecule magnets (SMMs). SMMs behave as molecular-size permanent magnets at low temperature and magnetic relaxation occurs by quantum tunneling processes; such molecules are promising candidates for use in quantum devices. We first discuss intramolecular ferromagnetic interactions for preparing high-spin molecules. Second, we determine the magnetic anisotropy for single metal ions with d" configurations and discuss how molecular anisotropy arises from single-ion anisotropy of the assembled component metal ions.