Two luminescent coordination polymers with a triple-helix structure:: HgX2(C31H24N2)•CH2Cl2 (X = Cl and Br)

被引：253

作者：

Ciurtin, DM ^{[1
]}

Pschirer, NG ^{[1
]}

Smith, MD ^{[1
]}

Bunz, UHF ^{[1
]}

zur Loye, HC ^{[1
]}

机构：

[1] Univ S Carolina, Dept Chem & Biochem, Columbia, SC 29208 USA

来源：

CHEMISTRY OF MATERIALS | 2001年 / 13卷 / 09期

关键词：

D O I：

10.1021/cm0103545

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The two new luminescent coordination polymers HgCl2(C31H24N2). CH2Cl2 (1) and HgBr2(C31H24N2). CH2Cl2 (2) feature helical zigzag chains intertwined in bundles of three. The luminescent properties of the isostructural compounds are due to the fluorene-based ligand 9,9-bis-ethyl-2,7-di-(4-pyridyl)ethynylfluorene and are red-shifted relative to those of the free ligand.

引用

页码：2743 / +

页数：4

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