Ruthenium and osmium complexes containing 2-(aminomethyl)pyridine (Ampy)-based ligands in catalysis

被引：96

作者：

Chelucci, Giorgio ^{[1
]}

Baldino, Salvatore ^{[2
]}

Baratta, Walter ^{[2
]}

机构：

[1] Univ Sassari, Dipartimento Agr, Viale Italia 39, I-07100 Sassari, Italy

[2] Univ Udine, Dipartimento Chim Fis Ambiente, I-33100 Udine, Italy

来源：

COORDINATION CHEMISTRY REVIEWS | 2015年 / 300卷

关键词：

Ruthenium complexes; Osmium complexes; Aminoalkylpyridines; Transfer hydrogenation; Hydrogenation; Catalysis; Asymmetric catalysis; N-HETEROCYCLIC CARBENE; ASYMMETRIC TRANSFER HYDROGENATION; DYNAMIC KINETIC RESOLUTION; ALLYLIC ALCOHOLS; CARBONYL-COMPOUNDS; EFFICIENT CATALYSTS; REDOX ISOMERIZATION; PINCER RUTHENIUM; DIASTEREOSELECTIVE REDUCTION; ENANTIOSELECTIVE CATALYSIS;

D O I：

10.1016/j.ccr.2015.04.007

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

This account focuses on the application in catalysis of ruthenium and osmium complexes containing 2-(aminomethyl)pyridine (Ampy)-based ligands. The combination of these aminoalkylpyridine ligands with appropriate phosphines affords ruthenium and osmium systems displaying unprecedented high catalytic activity and productivity in a variety of organic transformations such as hydrogenation by hydrogen transfer and dihydrogen, dehydrogenation, racemization, and alkylation. (C) 2015 Elsevier B.V. All rights reserved.

引用

页码：29 / 85

页数：57

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