Di-μ-oxo-bis[bis(bipyridine-N,N′)manganese(III,IV)] triperchlorate bis(nitrobenzene) hemihydrate

被引：5

作者：

Wilson, C

Larsen, FK

Figgis, BN

机构：

[1] Aarhus Univ, Dept Chem, DK-8000 Aarhus C, Denmark

[2] Univ Western Australia, Dept Chem, Nedlands, WA 6907, Australia

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1998年 / 54卷

关键词：

D O I：

10.1107/S0108270198008701

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The title compound, [Mn2O2(C10H8N2)(4)](ClO4)(3). 2C(6)H(5)-NO2. 0.5H(2)O, retains a half water molecule and incorporates two nitrobenzene molecules in the structure when recrystallized from a mixture of nitrobenzene and nitromethane. The two manganese sites have differing geometries suggestive of oxidation states Mn-III and Mn-IV. The supposed d(4) configuration of Mn-III implies a Jahn-Teller distortion, which is observed.

引用

页码：1797 / 1799

页数：3

共 50 条

[1] Di-μ-oxo-bis[bis(bipyridine-N,N prime )-manganese(III,IV)] triperchlorate bis(nitrobenzene) hemihydrate
Acta Crystallographica, Section C: Crystal Structure Communications, 1998, 54 (pt 12): : 1797 - 1799
[2] Di-μ-oxo-bis[(2,2′-bipyridine)cobalt(III)] bis(perchlorate)
Zhang, H
Chen, P
Fang, L
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2006, 62 : M934 - M935
[3] Tetrapyridinium di-μ-oxo-bis[trifluorotellurate(IV)] bis[pentafluorotellurate(IV)]
Klapötke, TM
Krumm, B
Mayer, P
Schwab, I
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2005, 61 : O2984 - O2986
[4] Synthesis and crystal structure of bis{oxo-bis[N,N-dimethylthiocarbamoylthioacetatodi-n-butyltin(IV)]} and bis{oxo-bis[N,N-diethylthiocarbamoylthioacetato Di-n-butyltin(IV)]}
Yin, HD
Xue, SC
Liu, GF
ACTA CHIMICA SINICA, 2004, 62 (06) : 603 - 609
[5] Hexaaqua[μ-di-μ-oxo-bis(hydroxodioxoiodate)] dieuropium(III) bis(perchlorate) dihydrate
Fischer, A
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2005, 61 : I262 - I264
[6] Synthesis and characterization of organotin compound bis{oxo-bis[(heteroaromatic carboxylato)di-n-butyltin(IV)]} and crystal structure of bis{oxo-bis[(2-thiophenylcarboxylato)di-n-butyltin(IV)]}
Yin, HD
Wang, CH
Xing, QJ
CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2004, 24 (07) : 770 - 774
[7] Di-(mu-pyrazolato-N:N')-bis[(2,2'-bipyridine-N,N')platinum(II)] bis(tetrafluoroborate) monohydrate
Sakai, K
Sato, T
Tsubomura, T
Matsumoto, K
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 1996, 52 : 783 - 786
[8] Syntheses and crystal structures of bis-[oxo-bis(p-ferrocenylbenzoxy di-n-propyltin)](I) and bis[oxo-bis(β-ferrocenoylpropionyloxy di-n-propyltin)](II)
Peng, B
Sun, LJ
Chang, WX
Xie, QL
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2003, 22 (06) : 647 - 652
[9] Syntheses and Crystal Structures of Bis-[oxo-bis(p-ferrocenylbenzoxy di-n-propyltin)](I) and Bis[oxo-bis(β-ferrocenoylpropionyloxy di-n-propyltin )](II)
PENG Bin SUN Li-Juan CHANG Wei-Xing XIE Qing-Lan② (National Key Laboratory of Elemento-Organic Chemistry
结构化学, 2003, (06) : 647 - 652
[10] Synthesis and characterization of bis-[oxo-bis(β-ferrocenyl trans-propenoic di-n-butyltin (IV)]
Lu, WG
Tao, JX
Li, XY
Wang, YZ
ACTA PHYSICO-CHIMICA SINICA, 2001, 17 (09) : 836 - 839

← 1 2 3 4 5 →