Oxygen transfer mechanism in the Mn-salen catalysed epoxidation of olefins

被引：16

作者：

Méou, A ^{[1
]}

Garcia, MA ^{[1
]}

Brun, P ^{[1
]}

机构：

[1] Univ Mediterranee, Fac Sci Luminy, GCOPL, CNRS,Lab Synth Organ Select, F-13288 Marseille 9, France

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 1999年 / 138卷 / 2-3期

关键词：

epoxidation; Mn-salen complexes; oxametallacycles;

D O I：

10.1016/S1381-1169(98)00168-X

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The Mn-salen catalysed epoxidation of geraniol and nerol derivatives or similar non-conjugated olefins, with H2O2 as oxidant, was studied. Along with the epoxide, rearranged products were isolated and characterised. The formation of these compounds is a strong argument in favour of the formation of an oxametallacycle as an intermediate in these epoxidation reactions. (C) 1999 Elsevier Science B.V. All rights reserved.

引用

页码：221 / 226

页数：6

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