Oxygen transfer mechanism in the Mn-salen catalysed epoxidation of olefins

被引：16

作者：

Méou, A ^{[1
]}

Garcia, MA ^{[1
]}

Brun, P ^{[1
]}

机构：

[1] Univ Mediterranee, Fac Sci Luminy, GCOPL, CNRS,Lab Synth Organ Select, F-13288 Marseille 9, France

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 1999年 / 138卷 / 2-3期

关键词：

epoxidation; Mn-salen complexes; oxametallacycles;

D O I：

10.1016/S1381-1169(98)00168-X

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The Mn-salen catalysed epoxidation of geraniol and nerol derivatives or similar non-conjugated olefins, with H2O2 as oxidant, was studied. Along with the epoxide, rearranged products were isolated and characterised. The formation of these compounds is a strong argument in favour of the formation of an oxametallacycle as an intermediate in these epoxidation reactions. (C) 1999 Elsevier Science B.V. All rights reserved.

引用

页码：221 / 226

页数：6

共 50 条

[21] Epoxidation of olefins catalyzed by manganese(III) salen complexes grafted to porous heterostructured clays [J].

Kuzniarska-Biernacka, Iwona ;

Pereira, Clara ;

Carvalho, Ana P. ;

Pires, Joao ;

Freire, Cristina .

APPLIED CLAY SCIENCE, 2011, 53 (02) :195-203

[22] CATALYTIC ACTIVITIES OF NICKEL(II) COMPLEXES OF A SALEN ANALOG, [NI(BABP)], IN EPOXIDATION OF OLEFINS [J].

YAMADA, M ;

OCHI, S ;

SUZUKI, H ;

HISAZUMI, A ;

KURODA, S ;

SHIMAO, I ;

ARAKI, K .

JOURNAL OF MOLECULAR CATALYSIS, 1994, 87 (2-3) :195-202

[23] Epoxidation of terminal olefins by oxygen catalysed by a mixture of manganese and cobalt slats of p-aminobenzoic acid supported on silica gel [J].

Hashemi, MM ;

Khoshabro, DK .

JOURNAL OF CHEMICAL RESEARCH, 2003, (10) :662-663

[24] Enantioselective epoxidation of chromenes using chiral Mn(III) salen catalysts with built-in phase-transfer capability [J].

Kureshy, RI ;

Khan, NUH ;

Abdi, SHR ;

Patel, ST ;

Iyer, PK ;

Jasra, RV .

TETRAHEDRON LETTERS, 2002, 43 (14) :2665-2668

[25] Asymmetric Mn(III)-salen catalyzed epoxidation of unfunctionalized alkenes with tetrabutylammonium monopersulfate [J].

Pietikäinen, P .

TETRAHEDRON LETTERS, 1999, 40 (05) :1001-1004

[26] Manganese(III) salen complexes anchored onto activated carbon as heterogeneous catalysts for the epoxidation of olefins [J].

Silva, AR ;

Figueiredo, JL ;

Freire, C ;

de Castro, B .

MICROPOROUS AND MESOPOROUS MATERIALS, 2004, 68 (1-3) :83-89

[27] Practical Epoxidation of Olefins Using Air and Ubiquitous Iron-Based Fluorous Salen Complex [J].

Kato, Yamato ;

Kanoh, Miho ;

Kobayashi, Hina ;

Shioiri, Takayuki ;

Matsugi, Masato .

MOLECULES, 2024, 29 (05)

[28] Amelioration of diet-induced nonalcoholic steatohepatitis in rats by Mn-salen complexes via reduction of oxidative stress [J].

Alireza Rezazadeh ;

Razieh Yazdanparast ;

Mahsa Molaei .

Journal of Biomedical Science, 19

[29] Polynuclear manganese complexes catalyzed epoxidation of olefins with molecular oxygen [J].

Krishnan, R ;

Vancheesan, S .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2002, 185 (1-2) :87-95

[30] Amelioration of diet-induced nonalcoholic steatohepatitis in rats by Mn-salen complexes via reduction of oxidative stress [J].

Rezazadeh, Alireza ;

Yazdanparast, Razieh ;

Molaei, Mahsa .

JOURNAL OF BIOMEDICAL SCIENCE, 2012, 19

← 1 2 3 4 5 →