Oxygen transfer mechanism in the Mn-salen catalysed epoxidation of olefins

被引：16
|
作者：
Méou, A [1 ]
Garcia, MA [1 ]
Brun, P [1 ]
机构：
[1] Univ Mediterranee, Fac Sci Luminy, GCOPL, CNRS,Lab Synth Organ Select, F-13288 Marseille 9, France
来源：
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 1999年 / 138卷 / 2-3期
关键词：
epoxidation; Mn-salen complexes; oxametallacycles;
D O I：
10.1016/S1381-1169(98)00168-X
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The Mn-salen catalysed epoxidation of geraniol and nerol derivatives or similar non-conjugated olefins, with H2O2 as oxidant, was studied. Along with the epoxide, rearranged products were isolated and characterised. The formation of these compounds is a strong argument in favour of the formation of an oxametallacycle as an intermediate in these epoxidation reactions. (C) 1999 Elsevier Science B.V. All rights reserved.
引用
收藏
页码：221 / 226
页数：6
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