Deep Eutectic Supramolecular Polymers: Bulk Supramolecular Materials

被引：158
作者：
Wu, Shuanggen [1 ]
Cai, Changyong [3 ]
Li, Fenfang [3 ]
Tan, Zhijian [2 ]
Dong, Shengyi [1 ]
机构：
[1] Hunan Univ, Coll Chem & Chem Engn, Changsha 410082, Hunan, Peoples R China
[2] Chinese Acad Agr Sci, Inst Bast Fiber Crops, Changsha 410205, Peoples R China
[3] Cent South Univ, Coll Chem & Chem Engn, Changsha 410083, Peoples R China
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2020年 / 59卷 / 29期
基金：
中国国家自然科学基金;
关键词：
deep eutectic solvents; materials science; polymers; self-assembly; supramolecular chemistry; MOLECULAR-RECOGNITION; IONIC LIQUIDS; RHEOLOGICAL BEHAVIOR; CITRIC-ACID; SOLVENTS; POLYMERIZATION; NETWORKS; COMPLEXES; HYDROGELS; SECONDARY;
D O I：
10.1002/anie.202004104
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Application of new strategies for supramolecular self-assembly can significantly impact the properties and/or functions of supramolecular polymers. To realize a facial strategy for the development of solvent-free supramolecular polymers in bulk, "deep eutectic solvents" were employed. Cyclodextrins and natural acids were used to prepare deep eutectic supramolecular polymers (DESPs). Deep eutectic solvents have special characteristics that endow DESPs with unique macroscopic properties and excellent processability. DESPs exhibit supramolecular adhesion and temperature-dependent behavior originating from the combined effects of deep eutectic solvents and supramolecular polymerization. Because DESPs are solvent-free and display interesting macroscopic properties, they have potential as new adaptive materials.
引用
收藏
页码：11871 / 11875
页数：5
相关论文
共 80 条
  • [1] Deep eutectic solvents formed between choline chloride and carboxylic acids: Versatile alternatives to ionic liquids
    Abbott, AP
    Boothby, D
    Capper, G
    Davies, DL
    Rasheed, RK
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (29) : 9142 - 9147
  • [2] Novel solvent properties of choline chloride/urea mixtures
    Abbott, AP
    Capper, G
    Davies, DL
    Rasheed, RK
    Tambyrajah, V
    [J]. CHEMICAL COMMUNICATIONS, 2003, (01) : 70 - 71
  • [3] New supramolecular ionic networks based on citric acid and geminal dicationic ionic liquids
    Aboudzadeh, M. Ali
    Munoz, M. Eugenia
    Santamaria, Antxon
    Mecerreyes, David
    [J]. RSC ADVANCES, 2013, 3 (23) : 8677 - 8682
  • [4] Facile Synthesis of Supramolecular Ionic Polymers That Combine Unique Rheological, Ionic Conductivity, and Self-Healing Properties
    Aboudzadeh, M. Ali
    Eugenia Munoz, M.
    Santamaria, Antxon
    Marcilla, Rebeca
    Mecerreyes, David
    [J]. MACROMOLECULAR RAPID COMMUNICATIONS, 2012, 33 (04) : 314 - 318
  • [5] Synthesis and Rheological Behavior of Supramolecular Ionic Networks Based on Citric Acid and Aliphatic Diamines
    Ali Aboudzadeh, M.
    Eugenia Munoz, M.
    Santamaria, Antxon
    Jose Fernandez-Berridi, M.
    Irusta, Lourdes
    Mecerreyes, David
    [J]. MACROMOLECULES, 2012, 45 (18) : 7599 - 7606
  • [6] Deep Eutectic Solvents: The Organic Reaction Medium of the Century
    Alonso, Diego A.
    Baeza, Alejandro
    Chinchilla, Rafael
    Guillena, Gabriela
    Pastor, Isidro M.
    Ramon, Diego J.
    [J]. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2016, 2016 (04) : 612 - 632
  • [7] [Anonymous], 2020, ANGEW CHEM, DOI [10.1002/ange.201914513, DOI 10.1002/ANGE.201914513]
  • [8] [Anonymous], ANGEW CHEM
  • [9] [Anonymous], 2010, Angew Chem Int Ed, DOI DOI 10.1002/ANGE.201002415
  • [10] Construction of Stimuli-Responsive Functional Materials via Hierarchical Self-Assembly Involving Coordination Interactions
    Chen, Li-Jun
    Yang, Hai-Bo
    [J]. ACCOUNTS OF CHEMICAL RESEARCH, 2018, 51 (11) : 2699 - 2710
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