Deep Eutectic Supramolecular Polymers: Bulk Supramolecular Materials

被引：157
|
作者：
Wu, Shuanggen [1 ]
Cai, Changyong [3 ]
Li, Fenfang [3 ]
Tan, Zhijian [2 ]
Dong, Shengyi [1 ]
机构：
[1] Hunan Univ, Coll Chem & Chem Engn, Changsha 410082, Hunan, Peoples R China
[2] Chinese Acad Agr Sci, Inst Bast Fiber Crops, Changsha 410205, Peoples R China
[3] Cent South Univ, Coll Chem & Chem Engn, Changsha 410083, Peoples R China
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2020年 / 59卷 / 29期
基金：
中国国家自然科学基金;
关键词：
deep eutectic solvents; materials science; polymers; self-assembly; supramolecular chemistry; MOLECULAR-RECOGNITION; IONIC LIQUIDS; RHEOLOGICAL BEHAVIOR; CITRIC-ACID; SOLVENTS; POLYMERIZATION; NETWORKS; COMPLEXES; HYDROGELS; SECONDARY;
D O I：
10.1002/anie.202004104
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Application of new strategies for supramolecular self-assembly can significantly impact the properties and/or functions of supramolecular polymers. To realize a facial strategy for the development of solvent-free supramolecular polymers in bulk, "deep eutectic solvents" were employed. Cyclodextrins and natural acids were used to prepare deep eutectic supramolecular polymers (DESPs). Deep eutectic solvents have special characteristics that endow DESPs with unique macroscopic properties and excellent processability. DESPs exhibit supramolecular adhesion and temperature-dependent behavior originating from the combined effects of deep eutectic solvents and supramolecular polymerization. Because DESPs are solvent-free and display interesting macroscopic properties, they have potential as new adaptive materials.
引用
收藏
页码：11871 / 11875
页数：5
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