A Single-Chain Magnet Tape Based on Hexacyanomanganate(III)

被引：37
作者：
Zhang, Yuan-Zhu [1 ]
Zhao, Han-Hua [1 ]
Funck, Edward [1 ]
Dunbar, Kim R. [1 ]
机构：
[1] Texas A&M Univ, Dept Chem, College Stn, TX 77842 USA
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2015年 / 54卷 / 19期
关键词：
hexacyanomanganate; long-range order; magnetic tape; single-chain magnets; DIMENSIONAL COORDINATION POLYMERS; MOLECULE-MAGNET; CRYSTAL-STRUCTURES; BRIDGED CLUSTERS; SPIN-CROSSOVER; RELAXATION; BEHAVIOR; MN; NANOWIRES; FE;
D O I：
10.1002/anie.201410664
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The tape-like chain {[(tptz)Mn-II(H2O)-Mn-III(CN)(6)](2)Mn-II(H2O)(2)}(n)center dot 4nMeOH center dot 2nH(2)O based on the anisotropic building block hexacyanomanganate(III) exhibits long-range magnetic ordering below 5.1 K as well as single-chain magnetic behavior at lower temperatures with an effective energy barrier of 40.5(7) K.
引用
收藏
页码：5583 / 5587
页数：5
相关论文
共 62 条
  • [1] Rational Design of a Photomagnetic Chain: Bridging Single-Molecule Magnets with a Spin-Crossover Complex
    Ababei, Rodica
    Pichon, Celine
    Roubeau, Olivier
    Li, Yang-Guang
    Brefuel, Nicolas
    Buisson, Lionel
    Guionneau, Philippe
    Mathoniere, Corine
    Clerac, Rodolphe
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2013, 135 (39) : 14840 - 14853
  • [2] [Anonymous], 2005, ANGEW CHEM, V117, P5991
  • [3] [Anonymous], 2003, ANGEW CHEM, V115, P521
  • [4] [Anonymous], 2001, ANGEW CHEM, V113, P1810
  • [5] [Anonymous], 2008, ANGEW CHEM, V120
  • [6] [Anonymous], 2003, ANGEW CHEM, V115, P1561
  • [7] [Anonymous], 2012, ANGEW CHEM, V124, P5209
  • [8] Reduced anionic Mn12 molecules with half-integer ground states as single-molecule magnets
    Aubin, SMJ
    Sun, ZM
    Pardi, L
    Krzystek, J
    Folting, K
    Brunel, LC
    Rheingold, AL
    Christou, G
    Hendrickson, DN
    [J]. INORGANIC CHEMISTRY, 1999, 38 (23) : 5329 - 5340
  • [9] A trigonal-bipyramidal cyanide cluster with single-molecule-magnet behavior:: Synthesis, structure, and magnetic properties of {[MnII(tmphen)2]3[MnIII(CN)6]2}
    Berlinguette, CP
    Vaughn, D
    Cañada-Vilalta, C
    Galán-Mascarós, JR
    Dunbar, KR
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (13) : 1523 - 1526
  • [10] A canted antiferromagnetic ordered phase of cyanido-bridged Mn2IIIReIV single-chain magnets
    Bhowmick, Indrani
    Hillard, Elizabeth A.
    Dechambenoit, Pierre
    Coulon, Claude
    Harris, T. David
    Clerac, Rodolphe
    [J]. CHEMICAL COMMUNICATIONS, 2012, 48 (78) : 9717 - 9719
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