Enhancement on the afterglow properties of Sr2MgSi2O7: Eu2+ by Er3+ codoping

被引:27
作者
Wu, Haoyi [1 ]
Hu, Yihua [1 ]
Chen, Li [1 ]
Wang, Xiaojuan [1 ]
机构
[1] Guangdong Univ Technol, Sch Phys & Optoelect Engn, Guangzhou 51006, Guangdong, Peoples R China
基金
中国国家自然科学基金;
关键词
Luminescence; Optical materials and properties; Phosphors; Thermoluminescence; LUMINESCENT PROPERTIES; LONG AFTERGLOW; DY3+; MECHANISM; PHOSPHOR;
D O I
10.1016/j.matlet.2011.05.079
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The Sr1.99MgSi2O7: Eu-0.01(2+), and Sr1.97MgSi2O7: Eu-0.01(2+), R-0.02(3+) (R: Dy, Er) are synthesized via high temperature solid-state reaction. The sample without codoping shows the highest luminescent efficiency, leading to the strongest emission intensity. Both Dy3+ and Er3+ enhance the afterglow properties. Compared with Dy3+, sample doped with Er3+ shows a longer afterglow duration because of a deeper trap and it may be the optimum codopant for Sr2MgSi2O7: Eu2+ long afterglow phosphors. (C) 2011 Elsevier B.V. All rights reserved.
引用
收藏
页码:2676 / 2679
页数:4
相关论文
共 14 条
[1]  
Alvani AAS, 2005, J LUMIN, V115, P147, DOI 10.1016/j.jlumin.2005.03.009
[2]   GLOW CURVES WITH GENERAL ORDER KINETICS [J].
CHEN, R .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1969, 116 (09) :1254-&
[3]   Comparison study of the luminescent properties of the white-light long afterglow phosphors: CaxMgSi2O5+x:Dy3+(x=1, 2, 3) [J].
Chen, Yonghu ;
Cheng, Xuerui ;
Liu, Miao ;
Qi, Zeming ;
Shi, Chaoshu .
JOURNAL OF LUMINESCENCE, 2009, 129 (05) :531-535
[4]   Mechanism of phosphorescence appropriate for the long-lasting phosphors Eu2+-doped SrAl2O4 with codopants Dy3+ and B3+ [J].
Clabau, F ;
Rocquefelte, X ;
Jobic, S ;
Deniard, P ;
Whangbo, MH ;
Garcia, A ;
Le Mercier, T .
CHEMISTRY OF MATERIALS, 2005, 17 (15) :3904-3912
[5]   Mechanism of persistent luminescence in Sr2MgSi2O7:Eu2+; Dy3+ [J].
Dorenbos, P .
PHYSICA STATUS SOLIDI B-BASIC SOLID STATE PHYSICS, 2005, 242 (01) :R7-R9
[6]  
Murayama Y., 1995, US Patent, Patent No. [5, 424, 006, 5424006]
[7]   Resolution of Eu2+ asymmetrical emission peak of SrAl2O4:Eu2+, Dy3+ phosphor by cathodoluminescence measurements [J].
Ngaruiya, J. M. ;
Nieuwoudt, S. ;
Ntwaeaborwa, O. M. ;
Terblans, J. J. ;
Swart, H. C. .
MATERIALS LETTERS, 2008, 62 (17-18) :3192-3194
[8]   XPES STUDIES OF OXIDES OF 2ND-ROW AND 3RD-ROW TRANSITION-METALS INCLUDING RARE-EARTHS [J].
SARMA, DD ;
RAO, CNR .
JOURNAL OF ELECTRON SPECTROSCOPY AND RELATED PHENOMENA, 1980, 20 (1-2) :25-45
[9]  
UWANIMO Y, 1986, B CHEM SOC JPN, V59, P2263
[10]   Persistent Luminescence in Eu2+-Doped Compounds: A Review [J].
Van den Eeckhout, Koen ;
Smet, Philippe F. ;
Poelman, Dirk .
MATERIALS, 2010, 3 (04) :2536-2566