Magnetite-polypyrrole core-shell structured microspheres and their dual stimuli-response under electric and magnetic fields

被引:84
作者
Park, Dae Eun [1 ]
Chae, Hyun Sik [1 ]
Choi, Hyoung Jin [1 ]
Maity, Arjun [2 ,3 ,4 ]
机构
[1] Inha Univ, Dept Polymer Sci & Engn, Inchon 402751, South Korea
[2] CSIR, DST CSIR Innovat Ctr, Natl Ctr Nanostruct Mat Mat Sci & Mfg, ZA-0001 Pretoria, South Africa
[3] Univ South Africa UNISA, Dept Civil & Chem Engn, Pretoria, South Africa
[4] Univ Johannesburg, Dept Appl Chem, ZA-2028 Johannesburg, South Africa
关键词
CARBONYL IRON PARTICLES; HIGH ELECTRORHEOLOGICAL ACTIVITY; MAGNETORHEOLOGICAL CHARACTERISTICS; COMPOSITE MICROSPHERES; SILICA PARTICLES; BARIUM-TITANATE; SUSPENSIONS; POLYANILINE; BEHAVIOR; FLUID;
D O I
10.1039/c5tc00007f
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Polypyrrole (PPy)-coated magnetite (Fe3O4) hybrid particles were synthesized under sonication. PPy was coated on the surface of Fe3O4 microspheres, whereas pyrrole monomers filled the interior of the Fe3O4 particles and were then polymerized. The s(t) ructure of the Fe3O4-PPy microspheres was confirmed by transmission electron microscopy. The electric and magnetic properties were confirmed by optical microscopy and vibrating sample magnetometry, respectively. The suspension of the Fe3O4-PPy composite microspheres dispersed in silicone oil exhibited both electrorheological and magnetorheological properties when measured using a rotational rheometer under an applied electric and magnetic field, respectively.
引用
收藏
页码:3150 / 3158
页数:9
相关论文
共 64 条
  • [1] Electrorheology of suspensions of mesostructured and mesoporous silica in poly(dimethylsiloxane)
    Agafonov, A. V.
    Nefedova, T. A.
    Davydova, O. I.
    [J]. COLLOID JOURNAL, 2008, 70 (05) : 535 - 540
  • [2] Preparation and characterization of carbonyl iron/poly(butylcyanoacrylate) core/shell nanoparticles
    Arias, J. L.
    Gallardo, V.
    Linares-Molinero, F.
    Delgado, A. V.
    [J]. JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2006, 299 (02) : 599 - 607
  • [3] Microfluidic production of monodisperse functional o/w droplets and study of their reversible pH dependent aggregation behavior
    Bauer, Wolfgang-Andreas C.
    Kotar, Jurij
    Cicuta, Pietro
    Woodward, Robert T.
    Weaver, Jonathan V. M.
    Huck, Wilhelm T. S.
    [J]. SOFT MATTER, 2011, 7 (09) : 4214 - 4220
  • [4] Hybrid magnetorheological elastomer: Influence of magnetic field and compression pressure on its electrical conductivity
    Bica, Ioan
    Anitas, Eugen M.
    Bunoiu, Madalin
    Vatzulik, Boris
    Juganaru, Iulius
    [J]. JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY, 2014, 20 (06) : 3994 - 3999
  • [5] PREPARATION AND ELECTRO-THERMOCONDUCTIVE CHARACTERISTICS OF MAGNETORHEOLOGICAL SUSPENSIONS
    Bica, Ioan
    Choi, Hyoung Jin
    [J]. INTERNATIONAL JOURNAL OF MODERN PHYSICS B, 2008, 22 (29): : 5041 - 5064
  • [6] Electrorheological characteristics of polyaniline/titanate composite nanotube suspensions
    Cheng, Qilin
    Pavlinek, Vladimir
    He, Ying
    Li, Chunzhong
    Saha, Petr
    [J]. COLLOID AND POLYMER SCIENCE, 2009, 287 (04) : 435 - 441
  • [7] Preparation of uniform titania microspheres with good electrorheological performance and their size effect
    Cheng, Yuchuan
    Guo, Jianjun
    Liu, Xuehui
    Sun, Aihua
    Xu, Gaojie
    Cui, Ping
    [J]. JOURNAL OF MATERIALS CHEMISTRY, 2011, 21 (13) : 5051 - 5056
  • [8] Facile Approach to Large-Scale Synthesis of 1D Calcium and Titanium Precipitate (CTP) with High Electrorheological Activity
    Cheng, Yuchuan
    Wu, Kaihua
    Liu, Fenghua
    Guo, Jianjun
    Liu, Xuehui
    Xu, Gaojie
    Cui, Ping
    [J]. ACS APPLIED MATERIALS & INTERFACES, 2010, 2 (03) : 621 - 625
  • [9] Synthesis and electrorheology of aniline/pyrrole copolymer
    Cho, CH
    Choi, HJ
    Kim, JW
    Jhon, MS
    [J]. JOURNAL OF MATERIALS SCIENCE, 2004, 39 (05) : 1883 - 1885
  • [10] Cole-cole analysis on dielectric spectra of electrorheological suspensions
    Choi, H. J.
    Hong, C. H.
    Jhon, M. S.
    [J]. INTERNATIONAL JOURNAL OF MODERN PHYSICS B, 2007, 21 (28-29): : 4974 - 4980