The synthesis of Ru/CNF colloidal catalysts: Comparison of ex-situ and in-situ methods

被引：2
|
作者：
Demidova, Yuliya S. [1 ,2 ]
Simakova, Irina L. [1 ,2 ]
Schubert, Tim [3 ]
Murzin, Dmitry Yu. [4 ]
机构：
[1] Boreskov Inst Catalysis, Novosibirsk, Russia
[2] Novosibirsk State Univ, Novosibirsk, Russia
[3] FutureCarbon GmbH, D-95448 Bayreuth, Germany
[4] Abo Akad Univ, Turku, Finland
来源：
MATERIALS TODAY-PROCEEDINGS | 2017年 / 4卷 / 11期
关键词：
ruthenium; colloidal synthesis; nanoparticles immobilization; CNF; hydrothermal stability; NANOPARTICLES;
D O I：
10.1016/j.matpr.2017.09.010
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
Carbon nanofibers supported Ru catalysts (Ru/CNF) were synthesized by the colloidal method, varying the immobilization procedure (i.e. ex-situ or in-situ method of Ru catalyst synthesis), and the reducing agent nature. Hydrothermal stability of the synthesized Ru catalysts was studied aiming on further application of these catalysts in aqueous phase transformations. The in-situ procedure of Ru catalyst synthesis was shown to give a higher Ru nanoparticles dispersion, while the ex-situ method provided a better size control and resistance to leaching under hydrothermal conditions as well as during the catalysts synthesis. (C) 2017 Elsevier Ltd. All rights reserved.
引用
收藏
页码：11364 / 11370
页数：7
相关论文
共 50 条
  • [1] Comparison of in-situ to ex-situ activities of bitumen-deactivated catalysts
    Chu, KS
    Dong, D
    Hanson, FV
    Massoth, FE
    INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 1996, 35 (11) : 4012 - 4019
  • [2] Comparison of in-situ to ex-situ activities of bitumen-deactivated catalysts
    Univ of Utah, Salt Lake City, United States
    Ind Eng Chem Res, 11 (4012-4019):
  • [3] An Insight into in-situ interactions through ex-situ methods
    Rajendran, S
    Vaibavi, S
    Anthony, N
    Trivedi, DC
    CORROSION AND CORROSION PROTECTION, 2001, 2001 (22): : 964 - 977
  • [4] Comparison of Ex-Situ and In-Situ Transesterification for the Production of Microbial Biodiesel
    Hazmi, Alia Tasnim
    Ahmad, Farah B.
    Athoillah, Ahdyat Zain
    Jameel, Ahmad Tariq
    BULLETIN OF CHEMICAL REACTION ENGINEERING AND CATALYSIS, 2021, 16 (04): : 733 - 743
  • [5] Comparison of ex-situ and in-situ nanoplasmonic platforms for detection and capture of exosomes
    Raju, Duraichelvan
    Bathini, Srinivas
    Badilescu, Simona
    Ghosh, Anirban
    Ouellette, Rodney J.
    Packirisamy, Muthukumaran
    SELECTED PROCEEDINGS FROM THE 233RD ECS MEETING, 2018, 85 (13): : 1407 - 1414
  • [6] Comparison of In-situ Nondestructive Testing and Ex-situ Methods in Additive Manufactured Specimens for Internal Feature Detection
    AbouelNour, Youssef
    Gupta, Nikhil
    RESEARCH IN NONDESTRUCTIVE EVALUATION, 2024, 35 (01) : 20 - 31
  • [7] Analytical Investigation of Fuel Cells by Using In-situ and Ex-situ Diagnostic Methods
    Schiller, G.
    Guelzow, E.
    Schulze, M.
    Wagner, N.
    Friedrich, K. A.
    THERMEC 2009, PTS 1-4, 2010, 638-642 : 1125 - 1130
  • [8] In-situ and ex-situ comparison of the electrochemical oxidation of SO2 on carbon supported Pt and Au catalysts
    Meekins, Benjamin H.
    Thompson, Anthony B.
    Gopal, Varsha
    Mehrabadi, Bahareh A. Tavakoli
    Elvington, Mark C.
    Ganesan, Prabhu
    Newhouse-Illige, Ty A.
    Shepard, Adam W.
    Scipioni, Lawrence E.
    Greer, James A.
    Weiss, John C.
    Weidner, John W.
    Colon-Mercado, Hector R.
    INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2020, 45 (03) : 1940 - 1947
  • [9] COMPARISON OF EX-SITU AND IN-SITU TECHNIQUES FOR BIOREMEDIATION OF HYDROCARBON-POLLUTED SOILS
    DOTT, W
    FEIDIEKER, D
    STEIOF, M
    BECKER, PM
    KAMPFER, P
    INTERNATIONAL BIODETERIORATION & BIODEGRADATION, 1995, 35 (1-3) : 301 - 316
  • [10] Comparison between SBR Compounds Filled with In-Situ and Ex-Situ Silanized Silica
    Bernal-Ortega, Pilar
    Anyszka, Rafal
    Morishita, Yoshihiro
    di Ronza, Raffaele
    Blume, Anke
    POLYMERS, 2021, 13 (02) : 1 - 15
12345