Theoretical Characterization of GaSb Colloidal Quantum Dots and Their Application to Photocatalytic CO2 Reduction with Water

被引:11
作者
Califano, Marco [1 ]
Rodosthenous, Panagiotis [1 ]
机构
[1] Univ Leeds, Sch Elect & Elect Engn, Pollard Inst, Leeds LS2 9JT, W Yorkshire, England
基金
英国工程与自然科学研究理事会;
关键词
nanocrystals; colloidal quantum dots; GaSb; pseudopotential method; k-vector analysis; direct-to-indirect transitions; OPTICAL-PROPERTIES; TEMPERATURE-DEPENDENCE; ELECTRON; CDSE; INP; OPTIMIZATION; CONFINEMENT; OSCILLATOR; OPERATION; ENERGIES;
D O I
10.1021/acsami.8b15492
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
With a large exciton Bohr radius and a high hole mobility in the bulk, GaSb is an important semiconductor material for technological applications. Here, we present a theoretical investigation into the evolution of some of its most fundamental characteristics at the nanoscale. GaSb emerges as a widely tunable, potentially disruptive new colloidal material with huge potential for application in a wide range of fields.
引用
收藏
页码:640 / 646
页数:7
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